A highly efficient process to enhance the bioleaching of spent lithium-ion batteries by bifunctional pyrite combined with elemental sulfur.

Bioleaching technologies have been shown to be an environmentally friendly and economically beneficial tool for extracting metals from spent lithium-ion batteries (LIBs). However, conventional bioleaching methods have exhibited low efficiency in recovering metals from spent LIBs. Therefore, relied on the sustainability principle of using waste to treat waste, this study employed pyrite (FeS2) as an energy substance with reducing properties and investigated its effects in combination with elemental sulfur (S0) or FeSO4 on metals bioleaching from spent LIBs. Results demonstrated that the bioleaching efficiency was significantly higher in the leaching system constructed with FeS2 + S0, than in the FeS2 + FeSO4 or FeS2 system. When the pulp densities of FeS2, S0 and spent LIBs were 10 g L-1, 5 g L-1 and 10 g L-1, respectively, the leaching efficiency of Li, Ni, Co and Mn all reached 100%. Mechanistic analysis reveals that in the FeS2 + S0 system, the activity and acid-producing capabilities of iron-sulfur oxidizing bacteria were enhanced, promoting the generation of Fe (Ⅱ) and reducible sulfur compounds. Simultaneously, bio-acids were shown to disrupt the structure of the LIBs, thereby increasing the contact area between Fe (Ⅱ) and sulfur compounds containing high-valence metals. This effectively promoted the reduction of high-valence metals, thereby enhancing their leaching efficiency. Overall, the FeS2 + S0 bioleaching process constructed in this study, improved the leaching efficiency of LIBs while also effectively utilizing waste, providing technical support for the comprehensive and sustainable management of solid waste.

Feasibility of low-intensity ultrasound treatment with hydroxylamine to accelerate the initiation of partial nitrification and allow operation under intermittent aeration.

Partial nitrification is a key aspect of efficient nitrogen removal, although practically it suffers from long start-up cycles and unstable long-term operational performance. To address these drawbacks, this study investigated the effect of low intensity ultrasound treatment combined with hydroxylamine (NH2OH) on the performance of partial nitrification. Results show that compared with the control group, low-intensity ultrasound treatment (0.10 W/mL, 15 min) combined with NH2OH (5 mg/L) reduced the time required for partial nitrification initiation by 6 days, increasing the nitrite accumulation rate (NAR) and ammonia nitrogen removal rate (NRR) by 20.4% and 6.7%, respectively, achieving 96.48% NRR. Mechanistic analysis showed that NH2OH enhanced ammonia oxidation, inhibited nitrite-oxidizing bacteria (NOB) activity and shortened the time required for partial nitrification initiation. Furthermore, ultrasonication combined with NH2OH dosing stimulated EPS (extracellular polymeric substances) secretion, increased carbonyl, hydroxyl and amine functional group abundances and enhanced mass transfer. In addition, 16S rRNA gene sequencing results showed that ultrasonication-sensitive Nitrospira disappeared from the ultrasound + NH2OH system, while Nitrosomonas gradually became the dominant group. Collectively, the results of this study provide valuable insight into the enhancement of partial nitrification start-up during the process of wastewater nitrogen removal.

A designed moderately thermophilic consortia with a better performance for leaching high grade fine lead-zinc sulfide ore.

Unwieldy fine sulfide ores are produced during mining; without being appropriately disposed of, they can cause environmental pollution and waste resources. This study investigated the leaching performance of a moderately thermophilic consortia (Leptospirillum ferriphilum + Acidithiobacillus caldus + Sulfobacillus benefaciens) for fine lead-zinc sulfide raw ore. The results showed this microbial community created a low pH, high ORP, and high cell concentration environment for mineral leaching, improving bioleaching efficiency. Under the action of this consortia, the zinc leaching rate reached 96.44 in 8 days, and reached 100% after 12 days. EPS analysis indicated that the consortia could mediate the secretion of more polysaccharides to ensure leaching efficiency. EPS levels and amino acids were the main factors affecting bioleaching. An analysis of mineral surface characteristics showed the consortia effectively leached pyrite and sphalerite from the fine sulfide ore, and prevented the mineral surface forming the jarosite that could hinder bioleaching. This study found that bioleaching reduced the potential environmental toxicity of the minerals, providing an important reference for guiding the bioleaching of unwieldy fine sulfide raw ore.

Calcium oxide modification of activated sludge as a low-cost adsorbent: Preparation and application in Cd(II) removal.

In this study, a simple to produce, low-cost and environment-friendly sludge based adsorbent, prepared from municipal dewatered sludge and modified by calcium oxide (CaO), is described. The enhancement effect of CaO modification on the adsorption capacity and mechanical strength of sludge based adsorbents (CaO-SA), and the modification mechanism of CaO on activated sludge are discussed. Also, the Cd(II) adsorption conditions are optimized using surface optimization experiment. The results indicated that CaO had a good effect on improving the adsorption capacity and mechanical strength of the sludge-based adsorbent. The CaO-SA adsorbent showed best performance with respect to the mechanical strength and Cd(II) adsorption capacity when prepared under 5% CaO dosage and 60 °C drying temperature. CaO modification can increase the specific surface area and calcium ion content of the sludge-based adsorbent and remove the proton of the carboxylic acid in the sludge. The Box-Behnken experimental design results revealed that the importance of operating conditions for CaO-SA adsorption of Cd(II) can be arranged in the order of adsorption time > dosage> pH> temperature. The results also indicated that the interactions between adsorption time and CaO-SA dosage, adsorption time and pH, adsorption time and temperature are all important factors affecting the Cd(II) adsorption. The optimal conditions (adsorption time of 90 min, CaO-SA dosage of 1 g/L, pH of 5 and adsorption temperature of 40 °C) for CaO-SA to adsorb Cd(II) were obtained by surface optimization, at which the Cd(II) adsorption rate could reach a value of 99.74%.

Bioleaching for detoxification of waste flotation tailings: Relationship between EPS substances and bioleaching behavior.

The production of large volumes of waste flotation tailings results in environmental pollution and presents a major ecological and environmental risk. This study investigates bioleaching of waste flotation tailings using Acidithiobacillus ferrooxidans. The experiments were performed with 5.00% solid concentration, pH 2.0 with 100 mL medium for 25 d in the lab. The pH, OPR, metal concentration, dissolved organic matter (DOM) in leachate and extracellular polymeric substances (EPS) were recorded. Bioleaching tailing materials were finally characterized. Results showed that microorganisms, acclimating with mine tailings, effectively accelerated the bioleaching process, achieving maximum Zn and Fe extraction efficiencies of 95.45% and 83.98%, respectively, after 25 days. Compared with raw mine tailings, bioleaching could reduce 96.36% and 95.84% leachable Zn and Pb, and Pb presented a low risk (4.13%), while Zn, Cu, and Cr posed no risk (0.34%, 0.64%, and 0%). Toxicity and environmental risk analysis revealed bioleaching process significantly reduced the environmental risk associated with mine tailings. EPS analysis indicated that the loosely-bound EPS (LB-EPS) and tightly-bound EPS (TB-EPS) fractions contained different organic substances, which played different roles in the bioleaching process. Pearson correlation analysis revealed that EPS was highly correlated with bioleaching behavior (p < 0.05), and EPS was the main factor affecting the bioleaching process, promoting bioleaching in the LB-EPS and TB-EPS fractions.

Preparation of High-Performance Activated Carbon from Coffee Grounds after Extraction of Bio-Oil.

In this study, a new method for economical utilization of coffee grounds was developed and tested. The resulting materials were characterized by proximate and elemental analyses, thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and N2 adsorption-desorption at 77 K. The experimental data show bio-oil yields reaching 42.3%. The optimal activated carbon was obtained under vacuum pyrolysis self-activation at an operating temperature of 450 °C, an activation temperature of 600 °C, an activation time of 30 min, and an impregnation ratio with phosphoric acid of 150 wt.%. Under these conditions, the yield of activated carbon reached 27.4% with a BET surface area of 1420 m2·g-1, an average pore size of 2.1 nm, a total pore volume of 0.747 cm3·g-1, and a t-Plot micropore volume of 0.428 cm3·g-1. In addition, the surface of activated carbon looked relatively rough, containing mesopores and micropores with large amounts of corrosion pits.

Simultaneous removal of Cr(VI) and acid orange 7 from water in pyrite-persulfate system.

As the industries advances at a fast pace, efficient and simultaneous removal of both heavy metals and organics from aqueous is essential to protecting public human health and environment. In this work, we used pyrite as reductant and catalyst for simultaneously reducing Cr(VI) and activating persulfate (PS) to degrade acid orange 7 (AO7). The results indicated that the simultaneous removal rate of AO7 and Cr(VI) by pyrite-PS was up to 100% within 60 min under acidic conditions. However, There was a competitive relationship between PS activation and Cr(VI) reduction for robbing Fe2+. At beginning of the reaction, the limited Fe2+ firstly activated persulfate rather than reduce Cr(VI). The effect of dosage of pyrite and PS on Cr(VI) reduction was more significant than that on AO7 degradation. Increased pyrite dosages from 1g·L-1 to 6 g L-1 resulted in enhanced Cr(VI) removal, and excessive PS (more than 0.4 g L-1) was not beneficial to Cr(VI) removal. Electron paramagnetic resonance (EPR) spectroscopy and radical scavenger studies demonstrated that sulfate (SO4-·), singlet oxygen (1O2) and superoxide radical (·O2-) were the crucial reactive oxygen species (ROS) in the pyrite-PS system rather than hydroxyl radical (·OH). This study showed that the pyrite-PS system could simultaneously remove AO7 and Cr(VI), which provided a new idea for the actual wastewater treatment.

Ultrasonic coupled bioleaching pretreatment for enhancing sewage sludge dewatering: Simultaneously mitigating antibiotic resistant genes and changing microbial communities.

In this study, ultrasonic as a pretreatment coupled with bioleaching was used to enhance sludge dewaterability. Changes in microbial diversity and antibiotic resistant genes (ARGs) were studied during the combined treatment process. The results show that under optimal conditions, combined ultrasonic and bioleaching treatment led to decreases in the specific resistance of filtration and bioleaching time by 7.59% and 12.5%, respectively, compared with single bioleaching process. Using high pressure filtration system, the water content of sludge cake treated by the combined treatment was decreased to 58.04%, which was 10.04% lower than bioleaching sludge. After combined treatment, the microbial diversity and the total number of bacteria in the sludge decreased significantly, which caused the decreases in the absolute abundance of sulfonamide and tetracycline ARGs by 1.56-1.58 and 0.34-1.23 log units, respectively. However, the decrease in the total bacterial biomass was greater than the decrease in the number of potential hosts carrying the tetracycline ARG, resulting in an increase in the relative abundance of tetracycline gene. Furthermore, this study proposed a mechanism of the dewatering and ARGs, involving the combined ultrasonic and bioleaching treatment: Firstly, ultrasonic cavitation causes extracellular polymeric substances (EPS) to fall off the surface of sludge; Secondly, this faster and directly makes bacteria cells affected by bio-acidification and bio-oxidation. In this case, the cells could be more easily destroyed by the combined ultrasonic and bioleaching treatment, compared with individual bioleaching treatment; As a result, stronger dewaterability and more removal rates of ARGs were achieved under the combined treatment. The economic analyses showed that the combined ultrasonic and bioleaching treatment is a more practical and economical technique for achieving deep dewatering of sludge.

Assessment of exposure to polybrominated diphenyl ethers associated with consumption of market hens in Guangzhou.

To evaluate contamination by polybrominated diphenyl ethers (PBDEs) in market hens and human PBDE exposure via hen consumption in Guangzhou, hens were collected and their muscle, liver, fat, blood, yolk, and ingluvies tissues were analyzed for 13 PBDE congeners. The median highest concentration of ∑PBDEs was found in the ingluvies (5.30 ng/g lw), followed by the muscle (2.53 ng/g lw), with the lowest located in the yolk (0.09 ng/g lw). The concentrations of PBDEs in the muscle tissue of market hens in Guangzhou were at medium levels compared to others reported around the world. BDE-47, -153, -99, and -183 were the predominant congeners. The daily intake concentrations of PBDEs from hen muscle were estimated to range from 0.08 to 0.31 ng/kg/day in this study, with a Hazard Quotient (HQ) below 1.0. These results suggest that the health risk of PBDEs for the general population, through the consumption of market hens in Guangzhou, was generally low. However, the intake of PBDEs via food consumption may be one major exposure pathway for the general population of Guangzhou.

Thermogravimetric Analysis of Textile Dyeing Sludge (TDS) in N2/CO2/O2 Atmospheres and its Combustion Model with Coal.

The combustion characteristics of textile dyeing sludge (TDS) in N2/O2, CO2/O2, and N2/CO2 atmospheres, and blends of TDS with coal were analyzed using TGA (thermogravimetric analysis). Results showed that the replacement of N2 by CO2 resulted in negative effects on the combustion and pyrolysis of TDS. Comparing N2/O2 and CO2/O2 atmospheres, combustion of TDS was easier in a N2/O2 atmosphere, but the residual mass after TDS pyrolysis in pure CO2 was less than that in N2 by approximately 4.51%. When the proportion of TDS was 30-50% in the blends of coal with TDS, a synergistic interaction clearly occurred, and it significantly promoted combustion. In considering different combustion parameters, the optimal proportion of TDS may be between 20-30%. The activation energy Ea value decreased from 155.6 kJ/mol to 53.35 kJ/mol with an increasing TDS proportion from 0% to 50%, and it rapidly decreased when the TDS proportion was below 20%.

Optimization of kinetics and operating parameters for the bioleaching of heavy metals from sewage sludge, using co-inoculation of two Acidithiobacillus species.

This study explores the potential for synchronous extraction of Cu, Cr, Ni and Zn during sewage sludge bioleaching processes, using three types of bacterial cultures: a pure culture of Acidithiobacillus ferrooxidans (A. ferrooxidans); a pure culture of Acidithiobacillus thiooxidans (A. thiooxidans); and a mixed culture of A. ferrooxidans and A. thiooxidans. Variable operating parameters included initial pH, solids concentration, sulfur concentration and ferrous iron concentration, with optimization via Box-Behnken design of response surface methodology. Results indicate that the mixed culture of A. ferrooxidans and A. thiooxidans, was the most effective at bioleaching heavy metals from sewage sludge. The optimal operating conditions were as follows: an initial pH of 2.0, with concentrations of 3% solids, 6.14 g L-1 sulfur and 4.55 g L-1 ferrous iron. Maximum extraction efficiencies obtained after 14 days of bioleaching under optimal conditions, were 98.54% Cu, 57.99% Cr, 60.06% Ni and 95.60% Zn. Bioleaching kinetics were effectively simulated using a shrinking core model to explain the leaching reaction, with modelling results suggesting that the rate was determined by the diffusion step.

Effects of toxic organic flotation reagent (aniline aerofloat) on an A/O submerged membrane bioreactor (sMBR): Microbial community dynamics and performance.

Bio-treatment of flotation wastewater has been proven to be both effective and economical, as a treatment method. Despite this, little is known regarding the effects of toxic organic floatation reagents such as Dianilinodithiophosphoric acid (DDA), on the microbial community performance or dynamics, which are critical to the effective performance of the bio-treatment reactor. A submerged membrane bioreactor (sMBR) was constructed to continuously treat simulated wastewater contaminated with DDA, an organic flotation reagent that is now considered a significant pollutant. The performance of the sMBR system was investigated at different DDA loading concentrations, with assessment of the effects of DDA on the microbial communities within the sMBR, in particular the biodiversity and succession within the microbial community. Results showed that, with increased DDA loadings, the performance of the sMBR was initially negatively affected, but the system adapted efficiently and consistently reached a COD removal rate of up to 80%. Increased DDA loading concentrations had an adverse effect on the activity of both the activated sludge and microbial communities, resulting in a large alteration in microbial dynamics, especially during the start-up stage and the high DDA loading stage. Strains capable of adapting to the presence of DDA, capable of degrading DDA or utilizing its byproducts, were enriched within the sMBR community, such as Zoogloea, Clostridium, Sideroxydans lithotrophicus, Thiobacillus, Thauera amino aromatica and Alicycliphilus denitrificans.

The effect of additives on migration and transformation of gaseous pollutants in the vacuum pyrolysis process of waste printed circuit boards.

The effect of six additives (CaCO3, HZSM-5, CaO, Al2O3, FeOOH and Ca(OH)2) on the generation, migration, transformation and escaping behaviours of typical gaseous pollutants in the pyrolysis process were studied by vacuum pyrolysis experiments on epoxy resin powder from waste printed circuit boards with tube furnace. The results show that the additives Al2O3, CaO, Ca(OH) 2 and FeOOH could reduce the yield of the gas phase. The removal rates of pollutants, such as benzene, toluene, ethyl benzene, phenol, p-xylene, HBr, NO2 and SO2 in the gaseous products, has changed variously with the increasing percentage of the above additives. Judging from the control of gas-phase pollutant discharge, the calcium-base additives are superior to the others. Ca(OH)2 has the best inhibition effect among them. The increase of the pyrolysis temperature and vacuum degree enhanced the volatility of organic pollutants and weakened the Ca(OH)2 inhibition effect on organic pollutants, while it improved the removal rate of SO2. Under the condition of 500 °C pyrolysis temperature and 0.09 MPa vacuum degree, when the additive proportion of Ca(OH)2 was one-fifth, the average removal rate of pollutants in gas phase is up to 66.4%.

Thermodynamic Equilibrium Calculations on Cd Transformation during Sewage Sludge Incineration.

Thermodynamic equilibrium calculations were performed to reveal the distribution of cadmium during the sewage sludge incineration process. During sludge incineration in the presence of major minerals, such as SiO2, Al2O3 and CaO, the strongest effect was exerted by SiO2 on the Cd transformation compared with the effect of others. The stable solid product of CdSiO3 was formed easily with the reaction between Cd and SiO2, which can restrain the emissions of gaseous Cd pollutants. CdCl2 was formed more easily in the presence of chloride during incineration, thus, the volatilization of Cd was advanced by increasing chlorine content. At low temperatures, the volatilization of Cd was restrained due to the formation of the refractory solid metal sulfate. At high temperatures, the speciation of Cd was not affected by the presence of sulfur, but sulfur could affect the formation temperature of gaseous metals.

Thermal Behavior of Cd During Sludge Incineration: Experiments and Thermodynamic Equilibrium Model.

Experiments and thermodynamic equilibrium calculations were performed to investigate the behavior of Cd during sewage sludge incineration. The chemical equilibrium calculations indicated that chlorine significantly increased the volatilization of Cd in the form of CdCl2. In addition, SiO2-containing materials can function as sorbents for stabilizing Cd. The effect of PVC added to the sludge on the migration of Cd in the sludge was greater than that of NaCl. As the temperature increased, both organic and inorganic chlorides reduced the Cd distribution in the bottom ash. The chloride concentration, and the incineration time exhibited insignificant changes in Cd emission. With the addition of either NaCl or PVC into the sludge, the phases of Cd present in the bottom slag were primarily present in the form of silica-alumina oxides or multi-metal oxide, which could inhabit the Cd volatilization.

Continuous treatment of flotation collector wastewater using a membrane bioreactor.

Aniline aerofloat (DDA) is a widely used material in China and has become a main pollutant in floatation wastewater. In this study, a membrane reactor (MBR) was constructed to continuously treat simulated wastewater contaminated with DDA. The study investigated the hydraulic retention time (HRT) and the impact of influent DDA concentration on MBR performance, and analyzed intermediates from the DDA biodegradation pathway and activated sludge transfer pathway. The results showed that a 3 h HRT was an efficient and economical time period for MBR to remove 95 ± 5 mg/L DDA from the simulated wastewater; the chemical oxygen demand reduction rate was 89.9%. DDA concentration negatively impacted MBR performance. MBR performance fluctuated slightly when HRT was 3 h, dissolved oxygen ranged from 4.8 to 5.3 mg/L, pH was between 6.5 and 7.0, and DDA concentrations were at 95 ± 5 mg/L DDA. The transfer pathway in the activated sludge of DDA was through soluble microbial products, loosely bound extracellular polymeric substances, tightly bound extracellular polymeric substances, and finally cell biodegradation. DDA initially degraded to aniline; the aniline was further biodegraded to other organic compounds and was finally mineralized through the tricarboxylic acid cycle. This study offers a new continuous biological treatment technology to address DDA.

Evaluating the primary and ready biodegradability of dianilinodithiophosphoric acid.

Dianilinodithiophosphoric acid (DDA) is widely used as sulfide mineral flotation collector in China. It is necessary to investigate the biodegradability of DDA to provide the fundamental knowledge to assess the environmental fate in the risk assessment of DDA and to design and operate the DDA flotation wastewater biological treatment plant. In the present study, the primary and ready aerobic biodegradations of DDA were studied and the primary biodegradation kinetic model of DDA was developed. The results show that DDA displays a good primary biodegradability and its biodegradation ratio reaches 99.8 % in 7 days. In contrast, DDA is not easily ready biodegradable; hence, it is a partially biodegradable organic compound. The primary aerobic biodegradation kinetics can be described using the first-order reaction kinetics equation: C = 19.72191e(-0.01513t).

An experimental and thermodynamic equilibrium investigation of the Pb, Zn, Cr, Cu, Mn and Ni partitioning during sewage sludge incineration.

The effects of different chlorides and operational conditions on the distribution and speciation of six heavy metals (Pb, Zn, Cr, Cu, Mn and Ni) during sludge incineration were investigated using a simulated laboratory tubular-furnace reactor. A thermodynamic equilibrium investigation using the FactSage software was performed to compare the experimental results. The results indicate that the volatility of the target metals was enhanced as the chlorine concentration increased. Inorganic-Cl influenced the volatilization of heavy metals in the order of Pb>Zn>Cr>Cu>Mn>Ni. However, the effects of organic-Cl on the volatility of Mn, Pb and Cu were greater than the effects on Zn, Cr and Ni. With increasing combustion temperature, the presence of organic-Cl (PVC) and inorganic-Cl (NaCl) improved the transfer of Pb and Zn from bottom ash to fly ash or fuse gas. However, the presence of chloride had no obvious influence on Mn, Cu and Ni. Increased retention time could increase the volatilization rate of heavy metals; however, this effect was insignificant. During the incineration process, Pb readily formed PbSiO4 and remained in the bottom ash. Different Pb compounds, primarily the volatile PbCl2, were found in the gas phase after the addition of NaCl; the dominant Pb compounds in the gas phase after the addition of PVC were PbCl2, Pb(ClO4)2 and PbCl2O4.

Production and characterization of polypropylene composites filled with glass fibre recycled from pyrolysed waste printed circuit boards.

Waste printed circuit boards (WPCBs) are composed of nearly 70% non-metals, which are generally recycled as low-value filling materials or even directly dumped in landfills. In this study, polypropylene (PP) composites reinforced by recycled pure glass fibres (RGF) from pyrolysed WPCBs were successfully produced. The manufacturing process, mechanical properties and thermal behaviour of the composites were investigated. The results showed that the appropriate addition of RGF in the composites can significantly improve the mechanical properties and thermal behaviour. When the added content of RGF was 30%, the maximum increment of tensile strength, impact strength, flexural strength and flexural modulus of the glass fibre (GF)/PP composites are 25.93%, 41.38%, 31.16% and 68.42%, respectively, and the vicat softening temperature could rise by 4.6°C. Furthermore, leaching of the GF/PP composites was also investigated. The GF/PP composites exhibited high performance and non-toxicity, offering a promising method to recycle RGF from pyrolysed WPCBs with high-value applications.

Triclocarban transformation and removal in sludge conditioning using chalcopyrite-triggered percarbonate treatment.

Herein, a facile combination approach of chalcopyrite and sodium percarbonate (CuFeS2+ SPC) was established to augment both TCC removal efficiency and sludge dewatering. Results showed that utilizing the CuFeS2 dosage of 600 mg/g total solids (TS) under the optimal condition, along with the SPC dosage of 12.5 mg/g TS, an initial pH of 4.0, and a reaction duration of 40 min, led to a substantial reduction of 53.9% in the TCC content within the sludge, accompanied by a notable decrease of 36.9% in the water content. Compared to well-studied iron-based advanced oxidation processes, CuFeS2 + SPC treatment proved to be more cost-effective and environmentally friendly. Mechanistic findings demonstrated that •OH oxidation played a significant role in TCC removal, with O2•- and 1O2 acting as secondary factors. During the CuFeS2 + SPC process, the received •OH, O2•-, and 1O2 destroyed the main binding sites of extracellular polymeric substances to TCC, including tryptophan-like protein, amide, CO stretch, and -COO- functional groups. As a result, approximately 50% of TCC was partially degraded within the solid sludge phase after the attack of radicals. Meanwhile, the decreased macromolecular organic compounds in solid sludge attenuated the binding efficacy of TCC, giving rise to the transfer of partial TCC to the liquid phase. Ultimately, the TCC in sludge was successfully removed, and five transformation products were identified. This study significantly contributes to our understanding regarding TCC transformation and removal in the sludge conditioning process.