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1.
Phys Chem Chem Phys ; 25(20): 14546-14551, 2023 May 24.
Artigo em Inglês | MEDLINE | ID: mdl-37191103

RESUMO

We have developed a self-propelled object, which is composed of a plastic cup and a camphor disk, on water to reflect its three-dimensional shape in the nature of motion. The self-propelled object, of which the driving force of motion is the difference in the surface tension, exhibited oscillatory motion between motion and rest. The period and the maximum speed of oscillatory motion increased and decreased depending on the height of the cup, h, respectively. Two types of diffusion coefficients were estimated based on the diffusion of camphor molecules which were indirectly visualized using 7-hydroxycoumarin. The experimental result on the period of oscillatory motion depending on h could be reproduced by the numerical calculation based on the diffusion of camphor molecules around the object and the diffusion coefficients which were experimentally estimated. The experimental results suggest that characteristic features of motion can be created based on the three-dimensional shape of the object.

2.
J Phys Chem B ; 125(6): 1674-1679, 2021 02 18.
Artigo em Inglês | MEDLINE | ID: mdl-33508193

RESUMO

The mode bifurcation between oscillatory motion and no motion of a camphor object floating on surfactant aqueous solution was investigated. The camphor and surfactant were used as the sources of driving and suppressing forces, respectively. A circular plastic sheet was attached to the center of the bottom of a camphor disk, which served as the self-propelled object; further, the contact area between the disk and the solution (S) was varied to control the amount of camphor molecules from the disk that dissolved in the solution. Motion features, that is, the maximum speed, frequency of oscillatory motion, and mode bifurcation, varied depending on S. We discussed the relationship between these motion features and the kinetics of camphor and surfactant molecules around the object. The results suggest that the nature of the oscillatory motion depends on the amount of camphor molecules accumulated at the base of the self-propelled object.

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