1.
J Am Chem Soc
; 130(39): 12840-1, 2008 Oct 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-18778060
RESUMO
We report here the results on single crystal X-ray crystallographic analysis of the Gd@C82 carbene adduct (Gd@C82(Ad), Ad = adamantylidene). The Gd atom in Gd@C82(Ad) is located at an off-centered position near a hexagonal ring in the C2v-C82 cage, as found for M@C82 (M = Sc and La) and La@C82(Ad). Theoretical calculation also confirms the position of the Gd atom in the X-ray crystal structure.