Health risks of solid waste management practices in rural Ghana: A semi-quantitative approach toward a solid waste safety plan.

Inadequate solid waste management (SWM) can lead to environmental contamination and human health risks. The health risks from poor SWM can vary based on specific practices and exposure pathways. Thus, it is necessary to adequately understand the local context. This information, however, is rarely available in low-resource settings, particularly in rural areas. A solid waste safety plan could be helpful in these settings for gathering necessary data to assess and minimize health risks. As a step in developing such a tool, a semi-quantitative health risk analysis of SWM practices in nine Ghanaian rural villages was undertaken. Data on SWM in each village were collected through qualitative field observations and semi-structured interviews with local stakeholders. SWM-related health risks were assessed using the collected data, similar case studies in the scientific literature and dialogue among an assembled team of experts. The analysis identified context-specific practices and exposure pathways that may present the most substantial health risks as well as targeted solutions for mitigation risks. A risk assessment matrix was developed to quantify SWM risks as low, medium, high, or very high based on the likelihood and severity of identified hazards. The highest SWM risks were identified from dumpsites and uncontrolled burying of solid waste. More specifically, a very high or high risk of infectious and vector-borne diseases from SWM in the villages was identified, both in the disposal of solid waste in dumpsites and uncontrolled burying of solid waste. Additionally, a very high or high risk of inhalation, ingestion or dermal contact with contaminants was found in the disposal of solid waste in dumpsites, open burning of waste and reuse of waste from dumpsites as compost. The results demonstrate the potential value of a solid waste safety plan and a parsimonious approach to collect key local data to inform its contents.

Preparation and applications of chitosan and cellulose composite materials.

Chitosan is a natural fiber, chemically cellulose-like biopolymer, which is processed from chitin. Its use as a natural polymer is getting more attention because it is non-toxic, renewable, and biocompatible. However, its poor mechanical and thermal strength, particle size, and surface area restrict its industrial use. Consequently, to improve these properties, cellulose and/or inorganic nanoparticles have been used. This review discusses the recent progress of chitosan and cellulose composite materials, their preparation, and their applications in different industrial sectors. It also discusses the modification of chitosan and cellulose composite materials to allow their use on a large scale. Finally, the recent development of chitosan composite materials for drug delivery, food packaging, protective coatings, and wastewater treatment are discussed. The challenges and perspectives for future research are also considered. This review suggests that chitosan and cellulose nano-composite are promising, low-cost products for environmental remediation involving a simple production process.

Pollution potential of dumping sites on surface water quality in Ethiopia using leachate and comprehensive pollution indices.

Municipal solid waste disposed of in illegal dumpsites pollutes the surface and groundwater. However, accurately determining these pollution levels is typically challenging for practitioners and decision-makers in developing countries. The purpose of this study is to use the leachate pollution index (LPI) to assess the contamination potential of uncontrolled dumping sites along the course of the Kulfo River in Arba Minch, Ethiopia. The comprehensive pollution index (CPI) approach was also utilized to assess the suitability of Kulfo River water quality for aquatic species. Leachate samples were collected from four uncontrolled dumping sites along the Kulfo River's course and analyzed for fifteen leachate characteristics necessary to quantify the LPI sub-indices. Water samples were taken from three monitoring stations along the river and examined for aquatic species suitability. When the leachate parameters were compared to the Indian limit for discharge of treated leachate, it was found that dumping sites posed a considerable risk of pollution to adjacent water resources. The overall LPI ranged from 23.34 to 27.35, which is higher than the discharge standard LPI of 5.69, indicating that dumping sites can threaten the surrounding water resources and human health. Based on the rating scale of CPI, at all monitoring stations, the river resulted severely polluted. Finally, appropriate strategies to reduce the pollution and the related mismanagement of solid waste were discussed. Combining LPI and CPI methods can represent a crucial tool for experts and decision-makers in developing countries to evaluate the pollution potential of dumping sites and water resource monitoring.

Municipal solid waste management in refugee hosting communities: Analysis of a case study in northern Jordan.

The Syrian civil war, which broke out in 2011, caused the displacement of more than one million refugees to Jordan. Most of them settled in the Northern Govenorates of Jordan. Due to this, the local services and infrastructures of the hosting communities, in particular the solid waste management (SWM), were put under great pressure. The aim of this study is to evaluate how the off-camp refugees impacted the SWM in the Greater Irbid Municipality (GIM; in the Irbid Governorate), both quantitatively and qualitatively. Data and results obtained from the studies carried out before the Syrian crisis are compared with data collected by the authors in 2016 using similar or comparable methodologies. Moreover, local citizen perceptions of and satisfaction with the solid waste (SW) service level were assessed. A deterioration of the SWM in GIM between 2011 and 2016 was observed in terms of service performance indicators (e.g., an increase of SW collection and transportation costs by 2.5 times and of fines for improper SW disposal by 2.2 times) and of citizens' views (a decline in SWM quality was felt by 59% of the respondents). An attempt to cope with this situation has been made in recent years with international donors mobilizing efforts and resources to enable municipalities to meet the growing demand in basic SW services. There is however, still much to be done.

Burkholderia thailandensis E264 as a promising safe rhamnolipids' producer towards a sustainable valorization of grape marcs and olive mill pomace.

Within the circular economy framework, our study aims to assess the rhamnolipid production from winery and olive oil residues as low-cost carbon sources by nonpathogenic strains. After evaluating various agricultural residues from those two sectors, Burkholderia thailandensis E264 was found to use the raw soluble fraction of nonfermented (white) grape marcs (NF), as the sole carbon and energy source, and simultaneously, reducing the surface tension to around 35 mN/m. Interestingly, this strain showed a rhamnolipid production up to 1070 mg/L (13.37 mg/g of NF), with a higher purity, on those grape marcs, predominately Rha-Rha C14-C14, in MSM medium. On olive oil residues, the rhamnolipid yield of using olive mill pomace (OMP) at 2% (w/v) was around 300 mg/L (15 mg/g of OMP) with a similar CMC of 500 mg/L. To the best of our knowledge, our study indicated for the first time that a nonpathogenic bacterium is able to produce long-chain rhamnolipids in MSM medium supplemented with winery residues, as sole carbon and energy source. KEY POINTS: • Winery and olive oil residues are used for producing long-chain rhamnolipids (RLs). • Both higher RL yields and purity were obtained on nonfermented grape marcs as substrates. • Long-chain RLs revealed stabilities over a wide range of pH, temperatures, and salinities.

Emerging technologies for biofuel production: A critical review on recent progress, challenges and perspectives.

Due to increasing anthropogenic activities, especially industry and transport, the fossil fuel demand and consumption have increased proportionally, causing serious environmental issues. This attracted researchers and scientists to develop new alternative energy sources. Therefore, this review covers the biofuel production potential and challenges related to various feedstocks and advances in process technologies. It has been concluded that the biofuels such as biodiesel, ethanol, bio-oil, syngas, Fischer-Tropsch H2, and methane produced from crop plant residues, micro- and macroalgae and other biomass wastes using thermo-bio-chemical processes are an eco-friendly route for an energy source. Biofuels production and their uses in industries and transportation considerably minimize fossil fuel dependence. Literature analysis showed that biofuels generated from energy crops and microalgae could be the most efficient and attractive process. Recent progress in the field of biofuels using genetic engineering has larger perspectives in commercial-scale production. However, its large-scale production is still challenging; hence, to resolve this problem, it is essential to convert biomass in biofuels by developing novel technology to increase biofuel production to fulfil the current and future energy demand.

Beneficial role of biochar addition on the anaerobic digestion of food waste: A systematic and critical review of the operational parameters and mechanisms.

The generation of huge amounts of food waste due to the increasing population is a serious global issue. The inadequate management of food waste and lack of proper handling approaches have created adverse negative impacts on the environment and the society. The use of traditional disposal (i.e. landfilling) and treatment (i.e. incineration and composting) methods are not considered to be efficient for managing food waste. Thus, anaerobic digestion (AD) has proven to be promising and cost-effective, as an alternative technology, for digesting and converting food waste into renewable energy and useful chemicals. However, mono-digestion of food waste suffers from process inhibition and instability which limit its efficiency. Adding biochar that has high buffering capacity and ensures optimum nutrient balance was shown to enhance biogas/methane production yields. This review reports on the physicochemical characteristics of food waste, the existing problems of food waste treatment in AD as well as the role of biochar amendments on the optimization of critical process parameters and its action mechanisms in AD, which could be a promising means of improving the AD performance. Also, this review provides insights regarding the selection of the desired/appropriate biochar characteristics, i.e. depending on the source of the feedstock and the pyrolysis temperature, and its role in enhancing biogas production and preventing the problem of process instability in the AD system. Finally, this review paper highlights the economic and environmental challenges as well as the future perspectives concerning the application of biochar amendments in AD.

Application of risk analysis to landfills in Italy: Developed and tested methodology at provincial level.

In the Italian authorization procedure for the construction of a landfill, the risk analysis (RA) is mandatory in case of request for derogation from the current legislation (Ministerial Decree (D.M.) 27 September 2010) in order to demonstrate that there is no risk for the environment. This paper describes the experience of the Province of Brescia, public body appointed for giving authorizations for new landfills, and its collaboration with the University of Brescia for the specific topic of RA applied to landfills. The research was undertaken because a lack of complete and specific indications about the application of such methodology to landfills has been identified. In particular, the province of Brescia faced the issue of verifying the proper application of such methodology in relevant cases. After referring to the legal and technical framework, including the current national legislation and a summary of the technical documents available for the topic (guidelines and instructions by technical bodies), the paper outlines the technical-preliminary approach applied by the Province of Brescia. This is complemented by a description of the methodological approach followed for RA for groundwater and for gaseous emissions, with a focus on biogas, together with the presentation of the results for three relevant case studies. The critical aspects that were faced and the proposal to overcome them, which are under discussion with the responsible bodies, are described as well.

WEEE treatment and system management in Italy and Serbia: A comparison.

Waste electrical and electronic equipment (WEEE) represent one of the growing waste streams in Europe, whose content of hazardous substances and valuable materials focus on how it is handled. However, there are differences between countries regarding e-waste management system in Europe. This paper analyses and presents data regarding the e-waste management system in Italy, one of the founding countries of the EU and Serbia - EU candidate country. Within this work, the following aspects were considered: legislative framework and EU directive goals in terms of e-waste, institutional setup, collection system, and existing recycling and treatment technologies. In addition, material flow analysis is used to model mass balance within WEEE treatment plants in both countries. Finally, through assessment and comparison of current systems in both countries, problems and shortages of Serbia's e-waste management system are addressed.

Material flow analysis and heavy hydrocarbon removal in a full-scale biopile and soil washing plant in northern Italy.

This study aimed to assess the mass fluxes and removal efficiencies of heavy hydrocarbons in a full-scale plant located in northern Italy. This plant receives and treats contaminated soil, soils and rocks from construction and demolition activities, incineration slags and street cleaning residues. The plant has three sections, consisting of bioremediation using biopile, a soil washing stage and a stabilization/solidification unit, which can perform independently or together with the others. The material flow analysis showed how the crisis in the construction industry changed the final destination of waste after the treatment: as the market demand for coarse material decreased, waste was sent directly to landfills for inert waste, instead of being recovered. Hydrocarbon mass fluxes showed that a considerable amount of pollutants was removed. In the period 2009-2014, the removal efficiencies of the bioremediation, the soil washing section and the entire plant were respectively 73%, 58% and 62%. The percentages of removal attained at the facility in study were sufficient to ensure the possibility of recovering the waste or disposing of it in different landfill categories, according to the national regulations.

Non-conventional stabilisation/solidification treatment of industrial wastes with residual powdered paints.

Stabilisation/solidification technologies are widely used for rendering industrial wastes inert. In this study, residual powdered paints were applied to treat different types of industrial wastes by stabilisation/solidification: Fumes from steel-making process, sludge from coagulation/flocculation treatments and powders from brushing and polishing metallic objects. Stabilisation/solidification trials were performed both under static conditions and in motion. It was observed that the residual paints could polymerise well in 60 min at 120 °C. The addition of water during the treatment resulted in highly porous and friable materials and, therefore, is not recommended. The mixture between wastes and paint influenced polymerisation. Specific heating conditions needed to be tested for each waste, varying from 80 °C to 150 °C. Significant reduction on leachability after treatment could be reached in most cases. Reduction on chlorides release up to 92.0% were achieved. Contents of other elements on the leachates, such as copper, molybdenum, nickel, zinc and dissolved organic carbon, could also be reduced in percentages up to 96.9%, 97.6%, 98.8%, 95.7% and 96.9%, respectively. For some types of wastes, however, especially those containing high contents of copper and mineral oils, the treatment was ineffective. Polymerisation in motion apparently improved binding capacity, but tests with increased content of paints are recommended to reduce the release of dissolved organic carbon.

Overcoming public health risks to staff during the management of waste from healthcare facilities.

Purpose The management of public health risks is a key focus for the European Union. One of the key factors that has been shown to pose a public health risk is that of the management of needles from healthcare facilities. The paper aims to discuss this issue. Design/methodology/approach Using audits of two case study hospitals based in northern Italy, this study sought to examine the key factors that resulted in needle stick injuries amongst staff and suggest measures to minimise these risks. Findings The number of needle stick injuries was influenced by various key factors including the time period during the year, the length of time employed, the location within the site, staff category and working hours. Practical implications Suggestions for overcoming the risk factors, including redesigning working patterns, staff training and awareness building, and the use of safety-engineered devices are outlined. Originality/value This study examined the incidence of needle stick injuries amongst healthcare staff in two Italian hospitals, which was lower than in other countries due to various factors, including recapping of needles not being allowed, the introduction of self-retractable needles and awareness campaigns about the correct disposal procedures of potentially infectious waste.

Costs associated with the management of waste from healthcare facilities: An analysis at national and site level.

Given rising spend on the provision of healthcare services, the sustainable management of waste from healthcare facilities is increasingly becoming a focus as a means of reducing public health risks and financial costs. Using data on per capita healthcare spend at the national level, as well as a case study of a hospital in Italy, this study examined the relationship between trends in waste generation and the associated costs of managing the waste. At the national level, healthcare spend as a percentage of gross domestic product positively correlated with waste arisings. At the site level, waste generation and type were linked to department type and clinical performance, with the top three highest generating departments of hazardous healthcare waste being anaesthetics (5.96 kg day-1 bed-1), paediatric and intensive care (3.37 kg day-1 bed-1) and gastroenterology-digestive endoscopy (3.09 kg day-1 bed-1). Annual overall waste management costs were $US5,079,191, or approximately $US2.36 kg-1, with the management of the hazardous fraction of the waste being highest at $US3,707,939. In Italy, reduction in both waste arisings and the associated costs could be realised through various means, including improved waste segregation, and linking the TARI tax to waste generation.

Environmental audits and process flow mapping to assess management of solid waste and wastewater from a healthcare facility: an Italian case study.

In Europe, there are an increasing number of policy and legislative drivers for a more sustainable approach to the management of natural resources as well as for the mitigation of environmental health risks. However, despite significant progress in recent years, there is still some way to go to achieve circularity of process, as well as risk mitigation within organisations. Using a case study of the Gardone Val Trompia hospital in northern Italy, this manuscript offers a novel holistic examination of strategies to enhance resource efficiency and environmental health within a key sector, i.e. the healthcare sector. Through the use of environmental audits and process flow mapping, trends in waste and wastewater arisings and the associated financial and environmental costs and risks were identified. Recommendations for developing more resource efficient approaches as well as mitigating the environmental and public health risks are suggested. These include strategies for improved resource efficiency (including reduction in the hazardous waste) and reduced environmental impacts during the containment, transport and treatment of the waste.

Resource recovery from waste by Roma in the Balkans: A case study from Zavidovici (BiH).

Roma communities represent the main involved actors in the informal activities in the Balkan regions, especially because the state does not formally recognize them as formal inhabitants. The Roma community in Zavidovici, despite being resident since the beginning of the 20th century, is still considered a marginalized and vulnerable group. They are actively involved in and dependent on the informal solid waste sector. Waste collection is a 'family business', a kind of self-employment and the main source of income for households. Informal recyclers have a central role in the solid waste management system and they recover a significant amount of materials, especially iron, copper, brass, lead and exhausted batteries. Despite the negative fluctuations of the raw material prices, because of the international economic crisis, informal recyclers remain dependent on the waste recycling sector. They are crucial actors in the value chain of recyclables: though they cannot access the final buyers of recyclables, they provide more than 50% of the market to the middle dealers in the Zenica-Doboj Canton. This research activity consists of a deep socio-economic analysis of the informal recyclers' community living in Zavidovici city. In particular, this paper describes the composition and welfare status of informal recyclers' households, the role of informal recyclers in waste collection, the geographical coverage and the related pattern of waste picking, types, volumes and price fluctuations of recyclable materials, and the middle dealers involved in the informal recycling system.

How to assess solid waste management in armed conflicts? A new methodology applied to the Gaza Strip, Palestine.

We have developed a new methodology for assessing solid waste management in a situation of armed conflict. This methodology is composed of six phases with specific activities, and suggested methods and tools. The collection, haulage, and disposal of waste in low- and middle-income countries is so complicated and expensive task for municipalities, owing to several challenges involved, that some waste is left in illegal dumps. Armed conflicts bring further constraints, such as instability, the sudden increase in violence, and difficulty in supplying equipment and spare parts: planning is very difficult and several projects aimed at improving the situation have failed. The methodology was validated in the Gaza Strip, where the geopolitical situation heavily affects natural resources. We collected information in a holistic way, crosschecked, and discussed it with local experts, practitioners, and authorities. We estimated that in 2011 only 1300 tonne day(-1) were transported to the three disposal sites, out of a production exceeding 1700. Recycling was very limited, while the composting capacity was 3.5 tonnes day(-1), but increasing. We carefully assessed system elements and their interaction. We identified the challenges, and developed possible solutions to increase system effectiveness and robustness. The case study demonstrated that our methodology is flexible and adaptable to the context, thus it could be applied in other areas to improve the humanitarian response in similar situations.

Emerging technologies for the removal of pesticides from contaminated soils and their reuse in agriculture.

Pesticides are becoming more prevalent in agriculture to protect crops and increase crop yields. However, nearly all pesticides used for this purpose reach non-target crops and remain as residues for extended periods. Contamination of soil by widespread pesticide use, as well as its toxicity to humans and other living organisms, is a global concern. This has prompted us to find solutions and develop alternative remediation technologies for sustainable management. This article reviews recent technological developments for remediating pesticides from contaminated soil, focusing on the following major points: (1) The application of various pesticide types and their properties, the sources of pesticides related to soil pollution, their transport and distribution, their fate, the impact on soil and human health, and the extrinsic and intrinsic factors that affect the remediation process are the main points of focus. (2) Sustainable pesticide degradation mechanisms and various emerging nano- and bioelectrochemical soil remediation technologies. (3) The feasible and long-term sustainable research and development approaches that are required for on-site pesticide removal from soils, as well as prospects for applying them directly in agricultural fields. In this critical analysis, we found that bioremediation technology has the potential for up to 90% pesticide removal from the soil. The complete removal of pesticides through a single biological treatment approach is still a challenging task; however, the combination of electrochemical oxidation and bioelectrochemical system approaches can achieve the complete removal of pesticides from soil. Further research is required to remove pesticides directly from soils in agricultural fields on a large-scale.

Best management practices for minimizing undesired effects of thermal remediation and soil washing on soil properties. A review.

The use of remediated soils as end-of-life materials raises some challenges including policy and regulation, permits and specifications, technological limitations, knowledge and information, costs, as well as quality and performance associated with using them. Therefore, a set of procedures must be followed to preserve the quality and fundamental properties of soil during a remediation process. This study presented a comprehensive review regarding the fundamental impacts of thermal desorption (TD) and soil washing (SW) on soil characteristics. The effects of main operating parameters of TD and SW on the physical, chemical, and biological properties of soil were systematically reviewed. In TD, temperature has a more remarkable effect on physic-chemical and biological characteristics of soil than heating time. Therefore, decrease in temperature within a suitable range prevents unreversible changes on soil properties. In SW, more attention should be paid to extraction process of contaminants from soil particles. Using the right dosage and type of chelating agents, surfactants, solvents, and other additives can help to avoid problems with recovery or treatment using conventional methods. In addition, this review introduced a framework for implementing sustainable remediation approaches based on a holistic approach to best management practices (BMPs), which, besides reducing the risks associated with different pollutants, might provide new horizons for decreasing the unfavourable impacts of TD and SW on soil.

Treatment of petroleum hydrocarbon contaminated soil by combination of electro-Fenton and biosurfactant-assisted bioslurry process.

Removing petroleum hydrocarbons (PHCs) from polluted soil is challenging due to their low bioavailability and degradability. In this study, an experiment was carried out to treat soil polluted with petroleum hydrocarbon using a hybrid electro-Fenton (with BDD anode electrode) and biological processes stimulated with long-chain rhamnolipids (biosurfactants). Electro-Fenton treatment was applied as a pretreatment before the biological process to enhance PHC biodegradability, which would benefit the subsequent biological process. The effects of initial pH, hydroxide concentration, soil organic matter composition, PHCs intermediates during the electro-Fenton process, and total numbers of bacteria in the biological process were analyzed to determine the optimum conditions. The results showed that the optimized electrolysis time for the electro-Fenton was 12 h. The change induced during pretreatment at a specified time was found suitable for the biological process stage and led to 93.6% PHC degradation in combination with the electro-Fenton-and-biological process after 72 h. The combined system's performance was almost 40% higher than individual electro-Fenton and biological treatments. GC-MS analysis confirms the formation of 9-octadecen-1-ol (Z), 2-heptadecene, 1-nonadecene, 1-heneicosene, and pentacosane as fragmentation during the PHCs degradation process. Thus, the electro-Fenton process as pretreatment combined with a biological process stimulated with rhamnolipids (biosurfactants) could be effectively applied to remediate soil polluted with PHCs. However, the system needs further research and investigation to optimize electrolysis time and biosurfactant dose to advance this approach in the soil remediation process.

Constraints to healthcare waste treatment in low-income countries - a case study from Somaliland.

In low-income countries, healthcare waste is mixed with the municipal waste stream and rarely receives special attention. This paper presents the lessons learned from a pilot project targeted to improve healthcare waste management in Hargeisa (Somaliland). The interventions were carried out in three of the main hospitals in the city. Consideration was also given to improve the overall situation regarding the management of healthcare waste. Three De Montfort incinerators were built and training was provided to operators, waste workers and healthcare personnel. Although the incinerators were constructed in accordance with the required standards, major constraints were identified in the operational phase: irregular de-ashing procedures, misuse of safety equipment, and ineffective separation of healthcare waste were seen in this phase. The paper concludes that in other small hospitals in the developing world, such as those in Hargeisa, on-site incineration by use of low-cost, small-scale incinerators could be successfully applied as an interim solution, provided that an agreed and acceptable plan of operation and maintenance is in place and responsibilities for the management of the facility are clearly identified. Moreover, when replicating this experience in other settings even greater importance should be given to the technical capacity building of operators and pressure should be exercised on local administrations in order to control and supervise the whole management system.