Overcoming the Contact Problem in Quantitative Attenuated Total Reflection Spectroscopy Analysis of Flat Samples.

A method for measuring the optical functions of a flat sample made of homogeneous and isotropic material, using attenuated total reflection spectroscopy when there is poor contact between the sample and the internal reflection element is presented. The approach consists in treating the spacing between the internal reflection element and the sample as an adjustable parameter, along with the dispersion model parameters, in the simultaneous fitting of s- and p-polarized spectra obtained when the gap distance is unknown. The method is tested with both synthetic and experimental (polystyrene) spectra. The results demonstrate the method's ability to accurately determine the optical functions even in the presence of a contact problem.

Infrared Optical Functions of Water Retrieved Using Attenuated Total Reflection Spectroscopy.

Comprehensive modeling of non-polarized infrared attenuated total reflection spectrum based on Fresnel equations and wavenumber-dependent dielectric function models of isotropic materials is shown to be a suitable and easy methodology to retrieve optical functions. The scheme is completely general and can be used even for strong dispersion and absorption resonances. Attenuated total reflection spectra in liquid water, measured in the spectral region 100-4400 cm-1 with diamond and germanium as internal reflection elements, were used to illustrate and evaluate the method. The refractive index of water computed from the dispersion analysis is critically compared with literature data.

Oriented single-crystal-like molecular arrangement of optically nonlinear 2-methyl-4-nitroaniline in electrospun nanofibers.

In-plane aligned nanofibers of organic 2-methyl-4-nitroaniline (MNA) were produced by the electrospinning technique using a 1:1 weight ratio with poly(l-lactic acid). The fibers are capable of enormous efficient optical second harmonic generation as strong as pure MNA crystals in powder form. Structural, spectroscopic, and second harmonic generation polarimetry studies show that the MNA crystallizes within the fibers in an orientation in which the aromatic rings of MNA are predominantly orientated edge-on with respect to the plane of the fiber array and with their dipole moments aligned with the fiber axis. The results show that the electrospinning technique is an effective method to fabricate all-organic molecular functional devices based on polymer nanofibers with guest molecules possessing strong nonlinear optical and/or polar properties.