Validity of forensic cartridge-case comparisons.

This article presents key findings from a research project that evaluated the validity and probative value of cartridge-case comparisons under field-based conditions. Decisions provided by 228 trained firearm examiners across the US showed that forensic cartridge-case comparison is characterized by low error rates. However, inconclusive decisions constituted over one-fifth of all decisions rendered, complicating evaluation of the technique's ability to yield unambiguously correct decisions. Specifically, restricting evaluation to only the conclusive decisions of identification and elimination yielded true-positive and true-negative rates exceeding 99%, but incorporating inconclusives caused these values to drop to 93.4% and 63.5%, respectively. The asymmetric effect on the two rates occurred because inconclusive decisions were rendered six times more frequently for different-source than same-source comparisons. Considering probative value, which is a decision's usefulness for determining a comparison's ground-truth state, conclusive decisions predicted their corresponding ground-truth states with near perfection. Likelihood ratios (LRs) further showed that conclusive decisions greatly increase the odds of a comparison's ground-truth state matching the ground-truth state asserted by the decision. Inconclusive decisions also possessed probative value, predicting different-source status and having a LR indicating that they increase the odds of different-source status. The study also manipulated comparison difficulty by using two firearm models that produce dissimilar cartridge-case markings. The model chosen for being more difficult received more inconclusive decisions for same-source comparisons, resulting in a lower true-positive rate compared to the less difficult model. Relatedly, inconclusive decisions for the less difficult model exhibited more probative value, being more strongly predictive of different-source status.

Droplet motion driven by humidity gradients during evaporation and condensation.

The motion of droplets on solid surfaces in response to an external gradient is a fundamental problem with a broad range of applications, including water harvesting, heat exchange, mixing and printing. Here we study the motion of droplets driven by a humidity gradient, i.e. a variation in concentration of their own vapour in the surrounding gas phase. Using lattice-Boltzmann simulations of a diffuse-interface hydrodynamic model to account for the liquid and gas phases, we demonstrate that the droplet migrates towards the region of higher vapour concentration. This effect holds in situations where the ambient gradient drives either the evaporation or the condensation of the droplet, or both simultaneously. We identify two main mechanisms responsible for the observed motion: a difference in surface wettability, which we measure in terms of the Young stress, and a variation in surface tension, which drives a Marangoni flow. Our results are relevant in advancing our knowledge of the interplay between gas and liquid phases out of thermodynamic equilibrium, as well as for applications involving the control of droplet motion.

Droplet Self-Propulsion on Slippery Liquid-Infused Surfaces with Dual-Lubricant Wedge-Shaped Wettability Patterns.

Young's equation is fundamental to the concept of the wettability of a solid surface. It defines the contact angle for a droplet on a solid surface through a local equilibrium at the three-phase contact line. Recently, the concept of a liquid Young's law contact angle has been developed to describe the wettability of slippery liquid-infused porous surfaces (SLIPS) by droplets of an immiscible liquid. In this work, we present a new method to fabricate biphilic SLIP surfaces and show how the wettability of the composite SLIPS can be exploited with a macroscopic wedge-shaped pattern of two distinct lubricant liquids. In particular, we report the development of composite liquid surfaces on silicon substrates based on lithographically patterning a Teflon AF1600 coating and a superhydrophobic coating (Glaco Mirror Coat Zero), where the latter selectively dewets from the former. This creates a patterned base surface with preferential wetting to matched liquids: the fluoropolymer PTFE with a perfluorinated oil Krytox and the hydrophobic silica-based GLACO with olive oil (or other mineral oils or silicone oil). This allows us to successively imbibe our patterned solid substrates with two distinct oils and produce a composite liquid lubricant surface with the oils segregated as thin films into separate domains defined by the patterning. We illustrate that macroscopic wedge-shaped patterned SLIP surfaces enable low-friction droplet self-propulsion. Finally, we formulate an analytical model that captures the dependence of the droplet motion as a function of the wettability of the two liquid lubricant domains and the opening angle of the wedge. This allows us to derive scaling relationships between various physical and geometrical parameters. This work introduces a new approach to creating patterned liquid lubricant surfaces, demonstrates long-distance droplet self-propulsion on such surfaces, and sheds light on the interactions between liquid droplets and liquid surfaces.

Suppression of crystallization in saline drop evaporation on pinning-free surfaces.

For sessile droplets of pure liquid on a surface, evaporation depends on surface wettability, the surrounding environment, contact angle hysteresis, and surface roughness. For non-pure liquids, the evaporation characteristics are further complicated by the constituents and impurities within the droplet. For saline solutions, this complication takes the form of a modified partial vapor pressure/water activity caused by the increasing salt concentration as the aqueous solvent evaporates. It is generally thought that droplets on surfaces will crystallize when the saturation concentration is reached, i.e., 26.3% for NaCl in water. This crystallization is initiated by contact with the surface and is thus due to surface roughness and heterogeneities. Recently, smooth, low contact angle hysteresis surfaces have been created by molecular grafting of polymer chains. In this work, we hypothesize that by using these very smooth surfaces to evaporate saline droplets, we can suppress the crystallization caused by the surface interactions and thus achieve constant volume droplets above the saturation concentration. In our experiments, we used several different surfaces to examine the possibility of crystallization suppression. We show that on polymer grafted surfaces, i.e., Slippery Omniphobic Covalently Attached Liquid-like (SOCAL) and polyethyleneglycol(PEGylated) surfaces, we can achieve stable droplets as low as 55% relative humidity at 25 °C with high reproducibility using NaCl in water solutions. We also show that it is possible to achieve stable droplets above the saturation concentration on other surfaces, including superhydrophobic surfaces. We present an analytical model, based on water activity, which accurately describes the final stable volume as a function of the initial salt concentration. These findings are important for heat and mass transfer in relatively low humidity environments.

Eyewitness confidence and decision time reflect identification accuracy in actual police lineups.

OBJECTIVE: Although there are many lab-based studies demonstrating the utility of confidence and decision time as indicators of eyewitness accuracy, there is almost no research on how well these variables function for lineups in the real world. In two experiments, we examined confidence and decision time associated with real lineups that had been conducted using research-based recommendations. HYPOTHESES: We expected that how confident an eyewitness sounded and how quickly that eyewitness made their identification would be associated with whether that eyewitness identified a suspect or a filler. We also hypothesized that people's interpretations of eyewitness confidence could be easily influenced by additional, biasing information. METHOD: Using audio recordings of these lineups, we examined (a) participants' subjective ratings of how confident an eyewitness sounded at the time of the identification and (b) objective data regarding how quickly the eyewitness made the identification decision. We also manipulated what additional information, if any, participants received in Experiment 2. RESULTS: In both experiments, decision time and confidence predicted whether the eyewitnesses identified the suspect or a known-innocent filler, and when decision time and confidence diverged, it is likely that the eyewitness identified a filler. In Experiment 2, we found that people's interpretations of eyewitness's confidence statements could be biased. When observers believed that the witness picked a filler rather than a suspect, or vice versa, this changed how confident they thought the witness sounded. CONCLUSIONS: Confidence and decision time should both be collected when administering real lineups, but objective decision time data may be the most useful because people's perceptions of confidence are easily altered. (PsycInfo Database Record (c) 2023 APA, all rights reserved).

The Liquid Young's Law on SLIPS: Liquid-Liquid Interfacial Tensions and Zisman Plots.

Slippery liquid-infused porous surfaces (SLIPS) are an innovation that reduces droplet-solid contact line pinning and interfacial friction. Recently, it has been shown that a liquid analogue of Young's law can be deduced for the apparent contact angle of a sessile droplet on SLIPS despite there never being contact by the droplet with the underlying solid. Since contact angles on solids are used to characterize solid-liquid interfacial interactions and the wetting of a solid by a liquid, it is our hypothesis that liquid-liquid interactions and the wetting of a liquid surface by a liquid can be characterized by apparent contact angles on SLIPS. Here, we first present a theory for deducing liquid-liquid interfacial tensions from apparent contact angles. This theory is valid irrespective of whether or not a film of the infusing liquid cloaks the droplet-vapor interface. We show experimentally that liquid-liquid interfacial tensions deduced from apparent contact angles of droplets on SLIPS are in excellent agreement with values from the traditional pendant drop technique. We then consider whether the Zisman method for characterizing the wettability of a solid surface can be applied to liquid surfaces created using SLIPS. We report apparent contact angles for a homologous series of alkanes on Krytox-infused SLIPS and for water-IPA mixtures on both the Krytox-infused SLIPS and a silicone oil-infused SLIPS. The alkanes on the Krytox-infused SLIPS follow a linear relationship in the liquid form of the Zisman plot provided that the effective droplet-vapor interfacial tension is used. All three systems follow a linear relationship on a modified Zisman plot. We interpret these results using the concept of the critical surface tension (CST) for the wettability of a solid surface introduced by Zisman. In our liquid surface case, the obtained critical surface tensions were found to be lower than the infusing liquid-vapor surface tensions.

Friction Coefficients for Droplets on Solids: The Liquid-Solid Amontons' Laws.

The empirical laws of dry friction between two solid bodies date back to the work of Amontons in 1699 and are pre-dated by the work of Leonardo da Vinci. Fundamental to those laws are the concepts of static and kinetic coefficients of friction relating the pinning and sliding friction forces along a surface to the normal load force. For liquids on solid surfaces, contact lines also experience pinning and the language of friction is used when droplets are in motion. However, it is only recently that the concept of coefficients of friction has been defined in this context and that droplet friction has been discussed as having a static and a kinetic regime. Here, we use surface free energy considerations to show that the frictional force per unit length of a contact line is directly proportional to the normal component of the surface tension force. We define coefficients of friction for both contact lines and droplets and provide a droplet analogy of Amontons' first and second laws but with the normal load force of a solid replaced by the normal surface tension force of a liquid. In the static regime, the coefficient of static friction, defined by the maximum pinning force of a droplet, is proportional to the contact angle hysteresis, whereas in the kinetic regime, the coefficient of kinetic friction is proportional to the difference in dynamic advancing and receding contact angles. We show the consistency between the droplet form of Amontons' first and second laws and an equation derived by Furmidge. We use these liquid-solid Amontons' laws to describe literature data and report friction coefficients for various liquid-solid systems. The conceptual framework reported here should provide insight into the design of superhydrophobic, slippery liquid-infused porous surfaces (SLIPS) and other surfaces designed to control droplet motion.

Self-Assembled, Hierarchical Structured Surfaces for Applications in (Super)hydrophobic Antiviral Coatings.

A versatile method for the creation of multitier hierarchical structured surfaces is reported, which optimizes both antiviral and hydrophobic (easy-clean) properties. The methodology exploits the availability of surface-active chemical groups while also manipulating both the surface micro- and nanostructure to control the way the surface coating interacts with virus particles within a liquid droplet. This methodology has significant advantages over single-tier structured surfaces, including the ability to overcome the droplet-pinning effect and in delivering surfaces with high static contact angles (>130°) and good antiviral efficacy (log kill >2). In addition, the methodology highlights a valuable approach for the creation of mechanically robust, nanostructured surfaces which can be prepared by spray application using nonspecialized equipment.

Lattice Boltzmann Simulations of Multiphase Dielectric Fluids.

The dynamic effect of an electric field on dielectric liquids is called liquid dielectrophoresis. It is widely used in several industrial and scientific applications, including inkjet printing, microfabrication, and optical devices. Numerical simulations of liquid-dielectrophoresis are necessary to understand the fundamental physics of the phenomenon, but also to explore situations that might be difficult or expensive to implement experimentally. However, such modeling is challenging, as one needs to solve the electrostatic and fluid dynamics equations simultaneously. Here, we formulate a new lattice-Boltzmann method capable of modeling the dynamics of immiscible dielectric fluids coupled with electric fields within a single framework, thus eliminating the need of using separate algorithms to solve the electrostatic and fluid dynamics equations. We validate the numerical method by comparing it with analytical solutions and previously reported experimental results. Beyond the benchmarking of the method, we study the spreading of a droplet using a dielectrowetting setup and quantify the mechanism driving the variation of the apparent contact angle of the droplet with the applied voltage. Our method provides a useful tool to study liquid-dielectrophoresis and can be used to model dielectric fluids in general, such as liquid-liquid and liquid-gas systems.

Eyewitnesses' free-report verbal confidence statements are diagnostic of accuracy.

OBJECTIVES: We assessed recent policy recommendations to collect eyewitnesses' confidence statements in witnesses' own words as opposed to numerically. We conducted an experiment to test whether eyewitnesses' free-report verbal confidence statements are as diagnostic of eyewitness accuracy as their numeric confidence statements and whether the diagnostic utility of eyewitnesses' verbal and numeric confidence statements varies across witnessing conditions. HYPOTHESES: We hypothesized that eyewitnesses' verbal and numeric confidence statements are both significantly associated with identification accuracy among choosers and that their diagnostic utility holds across varying witnessing conditions. METHOD: In the first phase of the experiment, eyewitnesses (N = 4,795 MTurkers; 48.8% female; 50.8% male; .3% other; age M = 36.9) viewed a videotaped mock-crime and made an identification decision from a culprit-present or culprit-absent lineup. We manipulated witnessing conditions at encoding and retrieval to obtain varied levels of memory performance. In the second phase of the experiment, evaluators (N = 456 MTurkers; 35.5% female; 62.7% male .4% other; age M = 36.5) translated witnesses' verbal confidence statements to a numeric estimate and we used calibration and confidence-accuracy characteristic analyses to compare the diagnosticity of witnesses' verbal and numeric confidence statements across the two levels of memory performance. RESULTS: Witnesses' verbal and numeric confidence statements were significantly and nondifferentially diagnostic of eyewitness accuracy for both choosers and nonchoosers, and their diagnostic utility held across variations in witnessing conditions. CONCLUSIONS: These findings suggest the applied utility of collecting either verbal or numeric confidence statements from eyewitnesses immediately following an identification decision. (PsycInfo Database Record (c) 2021 APA, all rights reserved).

Contact-Angle Hysteresis and Contact-Line Friction on Slippery Liquid-like Surfaces.

Contact-line pinning and dynamic friction are fundamental forces that oppose the motion of droplets on solid surfaces. Everyday experience suggests that if a solid surface offers low contact-line pinning, it will also impart a relatively low dynamic friction to a moving droplet. Examples of such surfaces are superhydrophobic, slippery porous liquid-infused, and lubricant-impregnated surfaces. Here, however, we show that slippery omniphobic covalently attached liquid-like (SOCAL) surfaces have a remarkable combination of contact-angle hysteresis and contact-line friction properties, which lead to very low droplet pinning but high dynamic friction against the motion of droplets. We present experiments of the response of water droplets to changes in volume at controlled temperature and humidity conditions, which we separately compare to the predictions of a hydrodynamic model and a contact-line model based on molecular kinetic theory. Our results show that SOCAL surfaces offer very low contact-angle hysteresis, between 1 and 3°, but an unexpectedly high dynamic friction controlled by the contact line, where the typical relaxation time scale is on the order of seconds, 4 orders of magnitude larger than the prediction of the classical hydrodynamic model. Our results highlight the remarkable wettability of SOCAL surfaces and their potential application as low-pinning, slow droplet shedding surfaces.

Policy and procedure recommendations for the collection and preservation of eyewitness identification evidence.

OBJECTIVE: The Executive Committee of the American Psychology-Law Society (Division 41 of the American Psychological Association) appointed a subcommittee to update the influential 1998 scientific review paper on guidelines for eyewitness identification procedures. METHOD: This was a collaborative effort by six senior eyewitness researchers, who all participated in the writing process. Feedback from members of AP-LS and the legal communities was solicited over an 18-month period. RESULTS: The results yielded nine recommendations for planning, designing, and conducting eyewitness identification procedures. Four of the recommendations were from the 1998 article and concerned the selection of lineup fillers, prelineup instructions to witnesses, the use of double-blind procedures, and collection of a confidence statement. The additional five recommendations concern the need for law enforcement to conduct a prelineup interview of the witness, the need for evidence-based suspicion before conducting an identification procedure, video-recording of the entire procedure, avoiding repeated identification attempts with the same witness and same suspect, and avoiding the use of showups when possible and improving how showups are conducted when they are necessary. CONCLUSIONS: The reliability and integrity of eyewitness identification evidence is highly dependent on the procedures used by law enforcement for collecting and preserving the eyewitness evidence. These nine recommendations can advance the reliability and integrity of the evidence. (PsycINFO Database Record (c) 2020 APA, all rights reserved).

Apparent Contact Angles on Lubricant-Impregnated Surfaces/SLIPS: From Superhydrophobicity to Electrowetting.

A fundamental limitation of liquids on many surfaces is their contact line pinning. This limitation can be overcome by infusing a nonvolatile and immiscible liquid or lubricant into the texture or roughness created in or applied onto the solid substrate so that the liquid of interest no longer directly contacts the underlying surface. Such slippery liquid-infused porous surfaces (SLIPS), also known as lubricant-impregnated surfaces, completely remove contact line pinning and contact angle hysteresis. However, although a sessile droplet may rest on such a surface, its contact angle can be only an apparent contact angle because its contact is now with a second liquid and not a solid. Close to the solid, the droplet has a wetting ridge with a force balance of the liquid-liquid and liquid-vapor interfacial tensions described by Neumann's triangle rather than Young's law. Here, we show how, provided the lubricant coating is thin and the wetting ridge is small, a surface free energy approach can be used to obtain an apparent contact angle equation analogous to Young's law using interfacial tensions for the lubricant-vapor and liquid-lubricant and an effective interfacial tension for the combined liquid-lubricant-vapor interfaces. This effective interfacial tension is the sum of the liquid-lubricant and the lubricant-vapor interfacial tensions or the liquid-vapor interfacial tension for a positive and negative spreading power of the lubricant on the liquid, respectively. Using this approach, we then show how Cassie-Baxter, Wenzel, hemiwicking, and other equations for rough, textured or complex geometry surfaces and for electrowetting and dielectrowetting can be used with the Young's law contact angle replaced by the apparent contact angle from the equivalent smooth lubricant-impregnated surface. The resulting equations are consistent with the literature data. These results enable equilibrium contact angle theory for sessile droplets on surfaces to be used widely for surfaces that retain a thin and conformal SLIPS coating.

Pinning-Free Evaporation of Sessile Droplets of Water from Solid Surfaces.

Contact-line pinning is a fundamental limitation to the motion of contact lines of liquids on solid surfaces. When a sessile droplet evaporates, contact-line pinning typically results in either a stick-slip evaporation mode, where the contact line pins and depins from the surface in an uncontrolled manner, or a constant contact-area mode with a pinned contact line. Pinning prevents the observation of the quasi-equilibrium constant contact-angle mode of evaporation, which has never been observed for sessile droplets of water directly resting on a smooth, nontextured, solid surface. Here, we report the evaporation of a sessile droplet from a flat glass substrate treated with a smooth, slippery, omni-phobic covalently attached liquid-like coating. Our characterization of the surfaces shows high contact line mobility with an extremely low contact-angle hysteresis of ∼1° and reveals a step change in the value of the contact angle from 101° to 105° between a relative humidity (RH) of 30 and 40%, in a manner reminiscent of the transition observed in a type V adsorption isotherm. We observe the evaporation of small sessile droplets in a chamber held at a constant temperature, T = (25.0 ± 0.1) °C and at constant RH across the range RH = 10-70%. In all cases, a constant contact-angle mode of evaporation is observed for most of the evaporation time. Furthermore, we analyze the evaporation sequences using the Picknett and Bexon ideal constant contact-angle mode for diffusion-limited evaporation. The resulting estimate for the diffusion coefficient, DE, of water vapor in air of DE = (2.44 ± 0.48) × 10-5 m2 s-1 is accurate to within 2% of the value reported in the literature, thus validating the constant contact-angle mode of the diffusion-limited evaporation model.

Droplet Retention and Shedding on Slippery Substrates.

A significant limitation for droplet mobility on solid surfaces is to overcome the inherent pinning of the droplet's contact line that occurs because of chemical/physical heterogeneities. A recent innovation is to use surface texture or porosity to create a stabilized lubricant surface. Droplets on such slippery liquid-infused porous surfaces (SLIPS)/lubricant-impregnated surfaces (LIS) are highly mobile because of the lubricant layer. Low pinning of the contact line reduces the energy required to move a droplet; however, it makes it difficult to accurately position the droplet or to stop its motion altogether. In this paper, a simple structure (step), as small as a few microns in height, is used to introduce controlled droplet pinning on a slippery substrate. The key effect is identified as the capillary force, arising from the interaction between the lubricant menisci created by the step and droplet. The effect of changing step height, lubricant thickness, and initial position on step-droplet interactions has been investigated, showing that droplets can both be repelled from and attracted to the step. To measure the adhesion strength, we report droplet detachment angle measurements under gravity and scaling of force with the lubricant thickness/step height ratio. Under certain conditions, the interaction strength is sufficient to ensure droplet-step attachment even when the surface is rotated to an upside-down orientation. These findings can motivate the design of SLIPS structures, capable of shedding or retaining droplets preferentially, for example, according to the size or wettability, relevant to applications from microfluidics to fog harvesting.

Four utilities in eyewitness identification practice: Dissociations between receiver operating characteristic (ROC) analysis and expected utility analysis.

The present article focuses on a utility-based understanding of criminal justice practice regarding eyewitness identifications. We argue that there are 4 distinct types of utility that should be considered when evaluating an identification procedure. These include the utility associated with all identifications, the utility associated with only the high confidence identifications, the average utility across the full range of identifications, and the maximum utility that can be attained by selecting an ideal criterion. We show that in almost all cases in which the difference between 2 procedures is defined by a tradeoff between increased guilty suspect IDs and increased innocent suspect IDs, current ROC (receiver operating characteristic) curve approaches fail to provide unambiguous information about which eyewitness identification procedures are best in practice. We introduce a novel graphical technique called utility difference curves that illustrates the impact that differential assumptions about base rates and cost structures have on the likely benefits of different identification procedures. The research emphasizes the importance of considering assumptions about base rates and costs associated with different types of eyewitness errors. We also clarify situations in which the outcome of eyewitness experiments are unambiguous and those in which careful consideration of tradeoffs are necessary. (PsycINFO Database Record (c) 2019 APA, all rights reserved).

Mistaken eyewitness identification rates increase when either witnessing or testing conditions get worse.

We examined how giving eyewitnesses a weak recognition experience impacts their identification decisions. In 2 experiments we forced a weak recognition experience for lineups by impairing either encoding or retrieval conditions. In Experiment 1 (n = 245), undergraduate participants were randomly assigned to watch either a clear or a degraded culprit video and then viewed either a culprit-present or culprit-removed lineup identification procedure. In Experiment 2 (n = 227), all participants watched the same clear culprit video but were then randomly assigned to either view a clear or noise-degraded lineup procedure. Half of the participants viewed a culprit-present lineup procedure and the remaining participants viewed a culprit-removed lineup procedure. Not surprisingly, degrading either encoding or retrieval conditions led to a sharp drop in culprit identifications. Critically, and as predicted, degrading either encoding or retrieval conditions also led to a sharp increase in the identification of innocent persons. These results suggest that when a lineup procedure gives a witness a weak match-to-memory experience, the witness will lower her criterion for making an affirmative identification decision. This pattern of results is troubling because it suggests that witnesses who encounter lineups that do not include the culprit might have a tendency to use a lower criterion for identification than do witnesses who encounter lineups that actually include the culprit. (PsycINFO Database Record (c) 2019 APA, all rights reserved).

Fillers can help control for contextual bias in forensic comparison tasks.

Forensic examiners are often exposed to contextual information that can bias their conclusions about evidence samples (e.g., fingerprints, fibers, tool marks). We tested the recently proposed filler-control method for moderating the biasing effects of contextual information for forensic comparisons. Borrowing from an analogy to eyewitness lineups versus showups, the filler-control method embeds a suspect's sample among known-innocent samples rather than the standard practice of presenting the analyst with only the suspect's sample for comparison. Our test of the filler-control method used fingerprints. After brief training, 234 participants compared eight sets of fingerprints in which suspect prints either matched the crime print or not, the prints were high or low in ambiguity, there was or was not contextual information suggesting there should be a match, and the suspect print was either embedded among filler prints or presented alone. Although the filler-control procedure reduced both hits and false alarms, the filler-control procedure produced better results overall as measured by d' analyses on suspect samples. These findings suggest the filler-control procedure should be considered for use in everyday forensic examination judgments, particularly when the error rate for a technique is unknown, or the risk of contextual bias is obvious, such as when examiners are called to make verification decisions. (PsycINFO Database Record

Eyewitness identification performance on showups improves with an additional-opportunities instruction: Evidence for present-absent criteria discrepancy.

We tested the proposition that when eyewitnesses find it difficult to recognize a suspect (as in a culprit-absent showup), eyewitnesses accept a weaker match to memory for making an identification. We tie this proposition to the basic recognition memory literature, which shows people use lower decision criteria when recognition is made difficult so as to not miss their chance of getting a hit on the target. We randomly assigned participant-witnesses (N = 610) to a condition in which they were told that if they did not believe the suspect was the culprit, they would have additional opportunities to make an identification later (additional-opportunities instruction). We fully crossed this instruction with the standard admonition (i.e., the culprit may or may not be present) and with the presence or absence of the culprit in a showup identification procedure. The standard admonition had no impact on eyewitness decision-making; however, the additional-opportunities instruction reduced innocent-suspect identifications (from 33% to 15%) to a greater extent than culprit identifications (57% to 51%). The additional-opportunities instruction yielded a better tradeoff between culprit and innocent-suspect identifications as indicated by binary logistic regression and receiver operator characteristic (ROC) analyses. (PsycINFO Database Record

Energy Invariance in Capillary Systems.

We demonstrate the continuous translational invariance of the energy of a capillary surface in contact with reconfigurable solid boundaries. We present a theoretical approach to find the energy-invariant equilibria of spherical capillary surfaces in contact with solid boundaries of arbitrary shape and examine the implications of dynamic frictional forces upon a reconfiguration of the boundaries. Experimentally, we realize our ideas by manipulating the position of a droplet in a wedge geometry using lubricant-impregnated solid surfaces, which eliminate the contact-angle hysteresis and provide a test bed for quantifying dissipative losses out of equilibrium. Our experiments show that dissipative energy losses for an otherwise energy-invariant reconfiguration are relatively small, provided that the actuation time scale is longer than the typical relaxation time scale of the capillary surface. We discuss the wider applicability of our ideas as a pathway for liquid manipulation at no potential energy cost in low-pinning, low-friction situations.