Metal Valence State Modulation Strategy to Design Core@shell Hollow Carbon Microspheres@MoSe2/MoOx Multicomponent Composites for Anti-Corrosion and Microwave Absorption.

The exploitation of multicomponent composites (MCCs) has become the main pathway for obtaining advanced microwave absorption materials (MAMs). Herein, a metal valence state modulation strategy is proposed to tune the electromagnetic (EM) parameters and improve microwave absorption performances. Core@shell hollow carbon microspheres@MoSe2 and hollow carbon microspheres@MoSe2/MoOx MCCs with various mixed-valence states content are well-designed and produced by a simple hydrothermal reaction or/and heat treatment process. The results reveal that the thermal treatment of hollow carbon microspheres@MoSe2 in Ar and Ar/H2 leads to the in situ formation of MoOx and multivalence state, respectively, and the enhanced content of Mo4+ in the designed MCCs greatly boosts their impedance matching characteristics, polarization, and conduction loss capacities, which lead to their evidently improved EM wave absorption properties. Amongst, the as-prepared hollow carbon microspheres@MoSe2/MoOx MCCs achieve an effective absorption bandwidth of 5.80 GHz under a matching thickness of 1.97 mm and minimum reflection loss of -21.49 dB. Therefore, this work offers a simple and universal method to fabricate core@shell hollow carbon microspheres@MoSe2/MoOx MCCs, and a novel and feasible metal valence state modulation strategy is proposed to develop high-efficiency MAMs.

Impacts of backscattering noises on upstream signals in full-duplex bidirectional PONs.

The backscattering noises introduced by Rayleigh and stimulated Brillouin scattering have been experimentally studied by means of their spectrum broadening, the scattering power variation and their impacts on upstream signals with different transmission fiber lengths and incident powers in a single-fiber bidirectional passive optical network (PON) communication system. The results show that both spontaneous scattering and simulated scattering can take place. The power and spectrum of backscattering noises are determined by the downstream launch power, laser linewidth and transmission fiber length. With the transmission length increasing, the power of backscattering noises gets higher, the spectrum of the backscattering noise broadens and the simulated threshold power decreases. The backscattering noise can beat with uplink light to modulate envelop of upstream signal resulting in degradation of BER greatly. Under the condition of one single channel for the second next generation PON (NG-PON2), the fiber length is 40km and downstream launch power is up to 11dBm. At this time, the backscattering noises are easy to be stimulated and the scattering power rises up from -20dBm to 10dBm, which can overwhelm the US signal. The spectrum of the optical beat interference noise also rises up with fiber length, which causes the uplink's BER degradation. The experimental results are significant for mitigation of backscattering noises under the condition of bidirectional PONs.