Insights into the Correlation of Microscopic Motions of [c2]Daisy Chains with Macroscopic Mechanical Performance for Mechanically Interlocked Networks.

Mimicking filament sliding in sarcomeres using artificial molecular muscles such as [c2]daisy chains has aroused increasing interest in developing advanced polymeric materials. Although few bistable [c2]daisy chain-based mechanically interlocked polymers (MIPs) with stimuli-responsive behaviors have been constructed, it remains a significant challenge to establish the relationship between microscopic responsiveness of [c2]daisy chains and macroscopic mechanical properties of the corresponding MIPs. Herein, we report two mechanically interlocked networks (MINs) consisting of dense [c2]daisy chains with individual extension (MIN-1) or contraction (MIN-2) conformations decoupled from a bistable precursor, which serve as model systems to address the challenge. Upon external force, the extended [c2]daisy chains in MIN-1 mainly undergo elastic deformation, which is able to assure the strength, elasticity, and creep resistance of the corresponding material. For the contracted [c2]daisy chains, long-range sliding motion occurs along with the release of latent alkyl chains between the two DB24C8 wheels, and accumulating lots of such microscopic motions endows MIN-2 with enhanced ductility and ability of energy dissipation. Therefore, by decoupling a bistable [c2]daisy chain into individual extended and contracted ones, we directly correlate the microscopic motion of [c2]daisy chains with macroscopic mechanical properties of MINs.

Low-temperature in situ preparation of Eu3+/Tb3+-doped CaMoO4/SrMoO4 nanoparticle thin films and their application in anti-counterfeiting.

Rare earth-doped metal oxide thin films exhibit remarkable potential for application in anti-counterfeiting, owing to their exceptional fluorescent properties. However, the existing fabrication techniques for these rare earth-doped luminescent thin films are predominantly complex and necessitate high-temperature conditions. In light of this issue, we present a low-temperature method for in situ fabrication of luminescent Ca1-xMoO4:Eux3+ and Sr1-xMoO4:Tbx3+ nanocrystal thin films by a solution deposition process. The developed method has the advantages of simple operation, rapid and low-temperature synthesis. The optimal chemical compositions of molybdate-based luminescent films are Ca0.90MoO4:Eu0.103+ and Sr0.90MoO4:Tb0.103+. Moreover, we evaluate the practical feasibility of luminescent nanoparticle films in the field of anti-counterfeiting by combining the unique fluorescent properties of rare earth ions and designing customized fluorescent patterns.