1.
Chem Commun (Camb)
; 59(51): 7959-7962, 2023 Jun 22.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37278987
RESUMO
The long-term cycling stability of LiCoO2 under high-voltage operation in lithium-ion batteries is still not satisfactory and the mechanism of capacity decay is not well understood. Here we mainly apply 17O MAS NMR spectroscopy to probe the phase transformation of cycled LiCoO2 cathodes in both liquid cells and solid cells. It turns out that deterioration into the spinel phase is the main cause.