RESUMO
Alkali ion rechargeable batteries play a significant part in portable electronic devices and electronic vehicles. The rapid development of renewable energy technology nowadays demands batteries with even higher energy density for grid storage. To fulfill such demand, extensive research efforts have been devoted to optimizing electrochemical properties as well as developing novel energy storage schemes and designing new systems. In the investigation process, synchrotron-based X-ray spectroscopy plays a vital role in investigating the detailed degradation mechanism and developing novel energy storage schemes. Herein, we critically review the applications of synchrotron-based X-ray spectroscopy in battery research in recent years. This review begins with a discussion of the different scientific issues in alkali ion rechargeable batteries within various time and space scales. Subsequently, the principle of synchrotron-based X-ray spectroscopy is introduced, and the characteristics of various characterization techniques are summarized and compared. Typical application cases of synchrotron-based X-ray spectroscopy are then introduced into battery investigations. The final part presents perspectives in the development direction of both alkali ion rechargeable battery systems and synchrotron-based X-ray spectroscopy in the future.