RESUMO
The successful utilization of silicon nanoparticles (Si-NPs) to enhance the performance of Li-ion batteries (LIBs) has demonstrated their potential as high-capacity anode materials for next-generation LIBs. Additionally, the availability and relatively low cost of sodium resources have a significant influence on developing Na-ion batteries (SIBs). Despite the unique properties of Si-NPs as SIBs anode material, limited study has been conducted on their application in these batteries. However, the knowledge gained from using Si-NPs in LIBs can be applied to develop Si-based anodes in SIBs by employing similar strategies to overcome their drawbacks. In this review, a brief history of Si-NPs' usage in LIBs is provided and discuss the strategies employed to overcome the challenges, aiming to inspire and offer valuable insights to guide future research endeavors.
RESUMO
Silicon has been proven to be one of the most promising anode materials for the next generation of lithium-ion batteries for application in batteries, the Si anode should have high capacity and must be industrially scalable. In this study, we designed and synthesised a hollow structure to meet these requirements. All the processes were carried out without special equipment. The Si nanoparticles that are commercially available were used as the core sealed inside a TiO2 shell, with rationally designed void space between the particles and shell. The Si@TiO2 were characterised using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). The optimised hollow-structured silicon nanoparticles, when used as the anode in a lithium-ion battery, exhibited a high reversible specific capacity over 630 mAhg-1, much higher than the 370 mAhg-1 from the commercial graphite anodes. This excellent electrochemical property of the nanoparticles could be attributed to their optimised phase and unique hollow nanostructure.