Impact of Strain Relaxation on 2D Ruddlesden-Popper Perovskite Solar Cells.

Although the photovoltaic performance of perovskite solar cells (PSCs) has reached the commercial standards, the unsatisfactory stability limits their further application. Hydrophobic interface and encapsulation can block the damage of water and oxygen, while the instability induced by intrinsic residual strain remains inevitable. Here, the residual strain in a two-dimensional (2D) Ruddlesden-Popper (RP) perovskite film is investigated by X-ray diffraction and atomic force microscopy. It's found that the spacer cations contribute to the residual strain even though they are not in the inorganic cages. Benefited from strain relaxation, the film quality is improved, leading to suppressed recombination, promoted charge transport and enhanced efficiency. More significantly, the strain-released devices maintain 86 % of the initial efficiency after being kept in air with 85 % relative humidity (RH) for 1080 h, 82 % under maximum power point (MPP) tracking at 50 °C for 804 h and 86 % after continuous heating at 85 °C for 1080 h.

Recent advances in non-fullerene organic photovoltaics enabled by green solvent processing.

Solution-processed organic photovoltaic (OPV) as a new energy device has attracted much attention due to its huge potential in future commercial manufacturing. However, so far, most of the studies on high-performance OPV have been treated with halogenated solvents. Halogenated solvents not only pollute the environment, but are also harmful to human health, which will negatively affect the large-scale production of OPV in the future. Therefore, it is urgent to develop low-toxic or non-toxic non-halogen solvent-processable OPV. Compared with conventional fullerene OPVs, non-fullerene OPVs exist with stronger absorption, better-matched energy levels and lower energy loss. Processing photoactive layers with non-fullerenes as the acceptor material has broad potential advantages in non-halogenated solvents. This review introduces the research progress of non-fullerene OPV treated by three different kinds of green solvents as the non-halogenated and aromatic solvent, the non-halogenated and non-aromatic solvent, alcohol and water. Furthermore, the effects of different optimization strategies on the photoelectric performance and stability of non-fullerene OPV are analyzed in detail. The current optimization strategy can increase the power conversion efficiency of non-fullerene OPV processed with non-halogen solvents up to 17.33%, which is close to the performance of processing with halogen-containing solvents. Finally, the commercial potential of non-halogen solvent processing OPVs is discussed. The green solvent processing of non-fullerene-based OPVs will become a key development direction for the future of the OPV industry.

Ultrastable and efficient slight-interlayer-displacement 2D Dion-Jacobson perovskite solar cells.

Stability has been a long-standing concern for solution-processed perovskite photovoltaics and their practical applications. However, stable perovskite materials for photovoltaic remain insufficient to date. Here we demonstrate a series of ultrastable Dion-Jacobson (DJ) perovskites (1,4-cyclohexanedimethanammonium)(methylammonium)n-1PbnI3n+1 (n ≥ 1) for photovoltaic applications. The scalable technology by blade-coated solar cells for the designed DJ perovskites (nominal n = 5) achieves a maximum stabilized power conversion efficiency (PCE) of 19.11% under an environmental atmosphere. Un-encapsulated cells by blade-coated technology retain 92% of their initial efficiencies for over 4000 hours under ~90% relative humidity (RH) aging conditions. More importantly, these cells also exhibit remarkable thermal (85 °C) and operational stability, which shows negligible efficiency loss after exceeding 5000-hour heat treatment or after operation at maximum power point (MPP) exceeding 6000 hours at 45 °C under a 100 mW cm-2 continuous light illumination.