Application of a Novel Liquid Nitrogen Control Technique for Heat Stress and Fire Prevention in Underground Mines.

With the continually increasing mining depths, heat stress and spontaneous combustion hazards in high-temperature mines are becoming increasingly severe. Mining production risks from natural hazards and exposures to hot and humid environments can cause occupational diseases and other work-related injuries. Liquid nitrogen injection, an engineering control developed to reduce heat stress and spontaneous combustion hazards in mines, was successfully utilized for environmental cooling and combustion prevention in an underground mining site named "Y120205 Working Face" (Y120205 mine) of Yangchangwan colliery. Both localized humidities and temperatures within the Y120205 mine decreased significantly with liquid nitrogen injection. The maximum percentage drop in temperature and humidity of the Y120205 mine were 21.9% and 10.8%, respectively. The liquid nitrogen injection system has the advantages of economical price, process simplicity, energy savings and emission reduction. The optimized heat exchanger used in the liquid nitrogen injection process achieved superior air-cooling results, resulting in considerable economic benefits.

Impact of heat and mass transfer during the transport of nitrogen in coal porous media on coal mine fires.

The application of liquid nitrogen injection is an important technique in the field of coal mine fire prevention. However, the mechanism of heat and mass transfer of cryogenic nitrogen in the goaf porous medium has not been well accessed. Hence, the implementation of fire prevention engineering of liquid nitrogen roughly relied on an empirical view. According to the research gap in this respect, an experimental study on the heat and mass transfer of liquid nitrogen in coal porous media was proposed. Overall, the main mechanism of liquid nitrogen fire prevention technology in the coal mine is the creation of an inert and cryogenic atmosphere. Cryogenic nitrogen gas vapor cloud, heavier than the air, would cause the phenomenon of "gravity settling" in porous media firstly. The cryogen could be applicable to diverse types of fires, both in the openings and in the enclosures. Implementation of liquid nitrogen open-injection technique in Yangchangwan colliery achieved the goals of fire prevention and air-cooling. Meanwhile, this study can also provide an essential reference for the research on heat and mass transfer in porous media in the field of thermal physics and engineering.

Study on key grouting blocking parameters of gas drainage boreholes in soft coal seams.

The construction of gas extraction boreholes in soft coal seams is prone to collapse and deformation, and grouting reinforcement is one of the main methods to solve the problem of efficient sealing. However, the reasonable selection of key grouting parameters still needs further research. In response to the problem of selecting grouting sealing parameters for gas drainage drilling in soft coal seams, based on the "concentric ring" reinforcement sealing technology obtained in previous research, the key parameters and sealing technology of the "concentric ring" reinforcement were studied through theoretical calculation and numerical simulation experiments. The slurry diffusion morphology and range under different grouting pressures and grouting time slurry viscosity were obtained. Finally, in order to explore the application effect of key grouting parameters, on-site industrial tests were conducted in a soft and high gas coal seam. The research results indicate that the optimal grouting pressure for the "retaining wall rock hole ring" should not be less than 3 MPa, the reasonable grouting time should be 10-15 min, and the water material ratio of the grouting material should be greater than 1:1; The use of new reinforcement sealing and grouting technology can ensure long-term good extraction effect. Compared to the testing of drilling sealing effect using ordinary cloth bags with two plugs and one injection, The adoption of new reinforcement sealing technology can effectively prevent the deformation and collapse of the borehole before sealing, and due to two rounds of grouting and pre reinforcement of fractured coal, the sealing effect of the borehole is also relatively good. The research results have important theoretical value for guiding the drilling and sealing grouting engineering of gas extraction in soft coal seams.

Quantifying the Resilience of Coal Energy Supply in China Toward Carbon Neutrality.

Facing the challenge of achieving the goal of carbon neutrality, China is decoupling the currently close dependence of its economy on coal use. The energy supply and demand decarbonization has substantial influence on the resilience of the coal supply. However, a general understanding of the precise impact of energy decarbonization on the resilience of the coal energy supply is still lacking. Here, from the perspective of network science, we propose a theoretical framework to explore the resilience of the coal market of China. We show that the processes of increasing the connectivity and the competition between the coal enterprises, which are widely believed to improve the resilience of the coal market, can undermine the sustainability of the coal supply. Moreover, our results reveal that the policy of closing small-sized coal mines may not only reduce the safety accidents in the coal production but also improve the resilience of the coal market network. Using our model, we also suggest a few practical policies for minimizing the systemic risk of the coal energy supply.

Coal dust dispersion with the moving conveyance in a high-rise building for the mine hoist system.

The present study investigates dust generated from the unloading process in a high-rise building for the mine hoist system and analyzes dust dispersion with the moving conveyance in the building. First, the gas-solid two-phase flow in the building was investigated based on the CFD-DPM method. In particular, the moving conveyance was considered in detail and treated via the dynamic mesh technology. Then, the airflow and dust distribution were investigated in the building. The airflow and the dust concentration at selected points show good agreement with the relative results of field measurements by ourselves. It is found that the descending conveyance significantly influences the surrounding flow field and the spatial and temporal distribution of dust. Dust concentration before the dust source (2 m × 2 m) is high, which extends downward with the conveyance. Dust concentration of the lower floors increases obviously when compared with that of the condition without the movement of the conveyance. The descending velocity of the conveyance also affects the amount of PM2.5 discharged from the return air outlet. The fitting functions are provided to predict PM2.5 emissions to the surrounding atmosphere. The research results are of great significance for the improvement of the dust control system for cleaner production technology.

Engineering solutions to breath tests based on an e-nose system for silicosis screening and early detection in miners.

This study aims to develop an engineering solution to breath tests using an electronic nose (e-nose), and evaluate its diagnosis accuracy for silicosis. Influencing factors of this technique were explored. 398 non-silicosis miners and 221 silicosis miners were enrolled in this cross-sectional study. Exhaled breath was analyzed by an array of 16 organic nanofiber sensors along with a customized sample processing system. Principal component analysis was used to visualize the breath data, and classifiers were trained by two improved cost-sensitive ensemble algorithms (random forest and extreme gradient boosting) and two classical algorithms (K-nearest neighbor and support vector machine). All subjects were included to train the screening model, and an early detection model was run with silicosis cases in stage I. Both 5-fold cross-validation and external validation were adopted. Difference in classifiers caused by algorithms and subjects was quantified using a two-factor analysis of variance. The association between personal smoking habits and classification was investigated by the chi-square test. Classifiers of ensemble learning performed well in both screening and early detection model, with an accuracy range of 0.817-0.987. Classical classifiers showed relatively worse performance. Besides, the ensemble algorithm type and silicosis cases inclusion had no significant effect on classification (p> 0.05). There was no connection between personal smoking habits and classification accuracy. Breath tests based on an e-nose consisted of 16× sensor array performed well in silicosis screening and early detection. Raw data input showed a more significant effect on classification compared with the algorithm. Personal smoking habits had little impact on models, supporting the applicability of models in large-scale silicosis screening. The e-nose technique and the breath analysis methods reported are expected to provide a quick and accurate screening for silicosis, and extensible for other diseases.

Field measurement and numerical simulation of dust migration in a high-rise building of the mine hoisting system.

Dust pollutants generated from the coal transfer process in a high-rise building of the mine hoisting system not only undermine the operating environment but also reduce the surrounding air quality. Therefore, this study aimed to determine the spatiotemporal distribution of coal dust in the high-rise buildings using field measurement and numerical simulation. Based on the discrete phase model (DPM), the dust migration process under the hybrid ventilation system was investigated in detail. Then, the feasibility of the established model to predict the spatiotemporal distribution of dust pollutants was proven through the measurements of both the airflow and the dust concentration. The present study showed that dust distribution is not uniform in time and space, which also differs for different floors. The dust concentration of the 3rd floor is relatively larger when compared with those of other floors. The dust concentration increases for the upper floors when the upward air velocity increases, while those of the lower floors are not always low due to the backflows, particularly for the 2nd floor. PM2.5 takes up more than 20% of all discharged particles.

Underground coal fire emission of spontaneous combustion, Sandaoba coalfield in Xinjiang, China: Investigation and analysis.

Long-term spontaneous combustion of coal has caused serious ecological and environmental problems. Only in recent years has it received growing popularity to undertake relevant researches. In order to study the impact of combustion by-products on atmosphere in the Sandaoba fire field, Xinjiang, a region-scale field survey was firstly conducted to investigate the gaseous-solid emissions in separated fire sections. The evaluation method and model have been proposed to describe the underground combustion and the related air pollution. Every year, the total estimates of the gaseous emission are approximately 4030 t of CO2, 113.6 t of SO2 and 57.3 t of CO. The emission pollution varies considerably from regions, and is substantially attenuated with the advancement of fire control. Principal component analysis (PCA) refines the thermophysical parameters into three attributions: the intrinsic thermophysical property, atmospheric dynamics, and combustion degree. PCA score distribution shows that thermophysical parameter is dominated by the combustion condition at severely polluted areas. Factor Analysis is used to extract four contaminant indicators, which suggests the local air suffers sulfur oxides pollution the most. The air quality index of the eight study sections calculated are all below 60, ranging from 24 to 58. It indicates that coal fire air pollution is in the medium-to-severe stage. By Canonical Correlation Analysis, it is noted that thermophysical indicator performs outstanding explanatory for contaminant variates. On the whole, the higher the level of thermophysical properties in the fire area, the greater the intensity of pollutant emission. Underground coalfield fire is dominated by smoldering, and the overall combustion efficiency is lower than 0.8 which generally declines as the excess air coefficient increasing.

Enrichment of Oxygen-Containing Low-Concentration Coalbed Methane with CMS-3KT as the Adsorbent.

A type of carbon molecular sieve (CMS-3KT) was used as the adsorbent for the CH4 enrichment of a methane/oxygen/nitrogen (CH4/O2/N2) mixture using micro-positive pressure vacuum pressure swing adsorption (∼120 kPa). The adsorption isotherms of individual CH4, O2, and N2 on CMS-3KT were studied and fitted. The results indicated the important influence of the adsorbent surface heterogeneity on the adsorption equilibrium process. In addition, the interaction of adsorbent-adsorbate in this process was studied from the measured adsorption heat. The adsorption uptake curves were fitted linearly with a classical micropore model for evaluating the kinetics-based separation possibility of CH4/O2/N2, and the corresponding diffusion time constants of CH4, O2, and N2 were calculated. Based on the results of adsorption equilibrium and kinetics, breakthrough experiments were employed to explore the upper limit value of methane concentration in feed gas such that methane can be enriched feasibly but difficultly. The breakthrough experiments were performed on the CH4/O2/N2 mixture with CH4 concentration ranging from 1 to 30%. Regarding industrial application, the O2 removal and CH4 enrichment performance of ultra-low-concentration methane (CH4 < 5%) were evaluated according to the results of the breakthrough experiment. The results indicated that the proposed method was promising for enriching O2-containing ultra-low-concentration CBM.

A catalyst powder-based spraying approach for rapid and efficient removal of fire-generated CO：From laboratory to pilot scale.

In confined space fires, the large amount of CO generated by incomplete combustion of carbon-based materials poses a serious threat to the trapped people. However, the efficient method of removing CO in such disasters remains a great challenge. Herein, a spraying catalyst powder (SCP) approach is proposed for CO removal by oxidizing CO to harmless CO2. Cu/Mn catalyst, synthesized by using ethylene glycol as solvent, was employed in this study. The influence of catalyst concentration, temperature, CO2 concentration and initial CO concentration on CO removal performance of SCP approach was investigated. With 500 g/m3 catalyst, 25,000 ppm CO could be reduced to 2550 ppm within 1 min and completely removed in less than 2.83 min at 200 °C. The feasibility of SCP approach in practical application was validated by the remarkable CO removal performance for charcoal combustion in confined tunnel. SCP approach could effectively reduce the CO concentration, which would reach up to 12,659 ppm in the absence of SCP approach, to less than 1500 ppm within 30 min. The experiment results suggest that SCP technology can effectively remove the fire-generated CO and is promising for practical application in crowded occupancies, such as underground space and aircraft compartment.

New Adsorption Models for Entirely Describing the Adsorption Isotherm and Heat of Methane in Heterogeneous Nanopore Structures of Coal.

To understand the adsorption mechanism of methane in heterogeneous nanopore structures of coal, integral adsorption models based on linear, exponential, hyperbolic and quadratic energy distribution functions are established. The adsorption energy domain of the new models is assumed to be a finite interval. These new adsorption models can describe both the adsorption isotherm and the adsorption heat. A volumetric method of adsorption with a microcalorimetry system is used to measure the adsorption isotherms and integral heat, and then the parameters of the new models are obtained by fitting the experimental data. Since the adsorption heat can be different for different adsorption models, it is necessary to fit the adsorption isotherms and heat simultaneously. The fitting results of the adsorption isotherms and heat show that the new models are able to describe the experimental data better than the Langmuir model. By comparing the fitting results and the effective range of adsorption energy of the different adsorption models, it is shown that the exponential energy distribution function is the most reasonable model for methane adsorption in coals, which can be used to evaluate the energetic heterogeneity of nanopores in coal samples. The decreasing exponential energy distributions of three coal samples indicate that a larger adsorption energy corresponds to fewer adsorption sites in the coal samples. The proportion of high adsorption energy is related to the micro-nanopore volume in the coal samples.

Selective Adsorption of CH4/N2 on Ni-based MOF/SBA-15 Composite Materials.

Spherical SBA-15-based metal⁻organic framework (MOF) composite materials were prepared, with nickel as the metal center of MOFs. The materials were characterized via scanning electron microscopy, X-ray fluorescence analysis, X-ray powder diffraction, Fourier-transform infrared spectroscopy, and nitrogen (N2) adsorption⁻desorption. The methane (CH4) or N2 high-pressure adsorption isotherms of the samples were measured and compared. The specific surface area and adsorption capacity of the composite materials were generally higher than the pristine MOFs, but were much lower than the synthesized SBA-15. The selectivity of the samples toward a binary gas mixture was determined from the Langmuir adsorption equation. The results revealed that, of all the samples, the MOF-2/SBA-15 sample had the best CH4/N2 adsorption selectivity, with an adsorption selection parameter (S) of 11.1. However, the adsorption of MOF-2/SBA-15 was less than that of spherical SBA-15, due to partial plugging of the pores during the synthesis process. Further research is essential for improving the performance of spherical SBA-15-based MOF materials and (in turn) the enrichment of CH4 from the CH4/N2 mixture.

Charge-Transfer Modeling and Polarization DRT Analysis of Proton Ceramics Fuel Cells Based on Mixed Conductive Electrolyte with the Modified Anode-Electrolyte Interface.

A charge-transfer model considering the mixed conductivities of proton, oxygen ion, and free electron in interface-modified La2Ce2O7 (LCO) electrolyte is designed to analyze the characteristics of proton ceramics fuel cell in the field of the open-circuit voltage, internal short-circuit current, proton-transfer number, discharging curves, oxygen/hydrogen partial pressure, and cell efficiencies. The properties of anode-supported single cells with the modified anode-electrolyte interface containing an in situ formed doped BaCeO3 reaction layer are compared to those of unmodified cells at various temperatures T and H2O partial pressures. Besides, the electrochemical impedance spectroscopies of both cells were investigated by the relaxation time distribution to distinguish different polarization processes. The results indicated that the reaction interface layer can effectively reduce the internal short-circuit current density and increase the proton-transfer number of electrolytes. Importantly, the NiO-BaZr0.1Ce0.7Y0.2O3-δ anode can also make more protons transfer from anode to cathode and participate in the cathodic reaction for LCO-based proton ceramics fuel cell. The polarization of the cell decreases with the increase of water partial pressure, which leads to the increase of open-circuit voltage and cell efficiency.

Clean Power Generation from the Intractable Natural Coalfield Fires: Turn Harm into Benefit.

The coal fires, a global catastrophe for hundreds of years, have been proved extremely difficult to control, and hit almost every coal-bearing area globally. Meanwhile, underground coal fires contain tremendous reservoir of geothermal energy. Approximately one billion tons of coal burns underground annually in the world, which could generate ~1000 GW per annum. A game-changing approach, environmentally sound thermal energy extraction from the intractable natural coalfield fires, is being developed by utilizing the waste energy and reducing the temperature of coalfield fires at the same time. Based on the Seebeck effect of thermoelectric materials, the temperature difference between the heat medium and cooling medium was employed to directly convert thermal energy into clean electrical energy. By the time of December 2016, the power generation from a single borehole at Daquan Lake fire district in Xinjiang has been exceeded 174.6 W. The field trial demonstrates that it is possible to exploit and utilize the waste heat resources in the treated coal fire areas. It promises a significant impact on the structure of global energy generation and can also promote progress in thermoelectric conversion materials, geothermal exploration, underground coal fires control and other energy related areas.