Novel delipidated chicken feather waste-derived carbon-based molybdenum oxide nanocomposite as efficient electrocatalyst for rapid detection of hydroquinone and catechol in environmental waters.

Chicken poultry industry produces a vast amount of feather waste and is often disposed into landfills, creating environmental pollution. Therefore, we explored the valorization of chicken feather waste into lipids and keratinous sludge biomass. This study demonstrates the successful utilization of keratinous sludge biomass as a unique precursor for the facile preparation of novel keratinous sludge biomass-derived carbon-based molybdenum oxide (KSC@MoO3) nanocomposite material using two-step (hydrothermal and co-pyrolysis) processes. The surface morphology and electrochemical properties of as-prepared nanocomposite material were analyzed using HR-SEM, XRD, XPS, and cyclic voltammetric techniques. KSC@MoO3 nanocomposite exhibited prominent electrocatalytic behavior to simultaneously determine hydroquinone (HQ) and catechol (CC) in environmental waters. The as-prepared electrochemical sensor showed excellent performance towards the detection of HQ and CC with broad concentration ranges between 0.5-176.5 µM (HQ and CC), and the detection limits achieved were 0.063 µM (HQ) and 0.059 µM (CC). Furthermore, the developed modified electrode has exhibited excellent stability and reproducibility and was also applied to analyze HQ and CC in environmental water samples. Results revealed that chicken feather waste valorization could result in sustainable biomass conversion into a high-value nanomaterial to develop a cost-effective electrochemical environmental monitoring sensor and lipids for biofuel.

Mechanism of dielectric barrier discharge plasma technology to improve the quantity of short-chain fatty acids in anaerobic fermentation of waste active sludge.

The mechanism of improving the anaerobic fermentation performance of waste active sludge by using dielectric barrier discharge (DBD) plasma pretreatment technology was investigated. The maximum accumulation of short-chain fatty acids (SCFAs) was observed on the 7th day of anaerobic fermentation when the DBD power was 76.50 W, which was 1726.70 mg COD/L, 1.50 times of the control group. The ratio of acetic acid in DBD group was 9.30% higher than that in the control. Further mechanism research indicated that DBD pretreatment can destroy the structure of extracellular polymer substances and release organic substances such as protein and polysaccharide. The dissolved organic matter analysis indicated that the DBD technique could increase the release of biodegradable organics (eg., tyrosine proteins, soluble microbial by-products), thus accelerate the biotransformation of organic substance. Bacterial community structure analysis showed that the increase in the abundance of Firmicutes and Bacteroidetes and the decrease in the abundance of Proteobacteria in DBD group were beneficial to the accumulation of SCFAs. Besides, further archaeal analysis indicated that the decrease of Methanosaeta sp. and Methanosarcina sp. abundance in the DBD group facilitate acetic acid accumulation. This study demonstrated that the DBD technique can be used as an effective and potential pretreatment method to improve sludge anaerobic fermentation performance.

Sludge Derived Carbon Modified Anode in Microbial Fuel Cell for Performance Improvement and Microbial Community Dynamics.

The conversion of activated sludge into high value-added materials, such as sludge carbon (SC), has attracted increasing attention because of its potential for various applications. In this study, the effect of SC carbonized at temperatures of 600, 800, 1000, and 1200 °C on the anode performance of microbial fuel cells and its mechanism are discussed. A pyrolysis temperature of 1000 °C for the loaded electrode (SC1000/CC) generated a maximum areal power density of 2.165 ± 0.021 W·m-2 and a current density of 5.985 ± 0.015 A·m-2, which is 3.017- and 2.992-fold that of the CC anode. The addition of SC improves microbial activity, optimizes microbial community structure, promotes the expression of c-type cytochromes, and is conducive to the formation of electroactive biofilms. This study not only describes a technique for the preparation of high-performance and low-cost anodes, but also sheds some light on the rational utilization of waste resources such as aerobic activated sludge.

Improved bio-electricity production in bio-electrochemical reactor for wastewater treatment using biomass carbon derived from sludge supported carbon felt anode.

Microbial fuel cell (MFC), a promising bio-electrochemical reactor could decompose organics in wastewater by redox processes of electro-active microorganism in anode and produce bio-energy, and the total MFC performance could mainly rely on electrochemical performance anode. Here, biomass carbon derived from municipal sludge was employed as low-cost and high-performance bio-anode for enhancing bioelectricity generation and wastewater treatment in MFC simultaneously. The electrochemical tests demonstrated that the large electrochemical active surface area, strong conductivity, and good biocompatibility in sludge carbon (SC) electrode resulted in higher power density (615.2 mW m-2) and lower power loss (5.4%) than those of none carbon (NC) electrode in long term operation. After 30-cycle of continuous running, the low loss of chemical oxygen demand (COD) removal was achieved up to 5.2%, which was smaller than that of NC electrode (14.1%), indicating that the MFC with SC anode could effectively treat wastewater and keep stable redox processes in anode electrode. After the formation of biofilm, the charge transfer resistance of SC electrode (16.38 Ω) was 72.4% lower than that of NC electrode (59.35 Ω). High-throughput analysis of biofilm exhibit Proteobacteria was the dominant electro-active bacteria, and the modification of SC could slightly change the bacterial community. Therefore, resource utilization of natural wastes provided the novel concept of anode catalyst fabrication for MFC in enhancing electron transfer, power output and wastewater decomposition.

Developing a high-quality catalyst from the pyrolysis of anaerobic granular sludge: Its application for m-cresol degradation.

This study proposes a novel approach for utilizing granular sludge discharged from anaerobic reactors to prepare an effective and stable catalyst for the removal of refractory contaminants in catalytic wet peroxide oxidation (CWPO). By implementing the response surface methodology, the experimental conditions for m-cresol degradation in CWPO with a HNO3-modified sludge carbon (GSC-M) as catalyst were explored. The removal efficiencies for m-cresol and total organic carbon (TOC) were 100% and 91.4%, respectively, at the optimal conditions of 60 °C for 120 min with a pH of 3, H2O2 dosage of 1.85 g/L, and catalyst dosage of 0.75 g/L. A continuous experiment was conducted for 6 d to investigate the durability and catalytic performance of GSC-M, resulting in a TOC removal above 90% with the catalyst maintaining its original morphology. GSC-M catalyst exhibited excellent stability and low iron leaching (0.34%). The high catalytic degradation could be attributed to a high content of iron species, various types of surface functional groups, porous structures, and the π-π interaction between aromatic clusters in sludge carbon and the benzene ring of m-cresol. Interestingly, GSC-M catalyst exhibited magnetic properties which are beneficial for recycling. Based on the identified intermediates, a possible degradation pathway of m-cresol was proposed.

Comparation of thermophilic bacteria (TB) pretreated primary and secondary waste sludge carbon sources on denitrification performance at different HRTs.

In this study, thermophilic bacteria pretreated primary and secondary waste sludge hydrolysis and acidification liquid were used as denitrification carbon sources at different HRTs (hydraulic retention time). The NO3--N removal rate of 99.3%, 99.0%, 99.9% and 99.2% was achieved at the optimal HRT of 8, 8, 4 and 6 h, respectively. Meanwhile, the utilization of COD (Chemical oxygen demand), proteins, carbohydrates, and VFAs (Volatile fatty acids) in carbon source during denitrification was also investigated. High-throughput sequencing technology showed that the microbial community changed with the different sludge carbon sources. And the dominant genus in both reactors was Thauera, which played a key role in denitrification.

Synthesis of sewage sludge-based carbon/TiO2 /ZnO nanocomposite adsorbent for the removal of Ni(II), Cu(II), and chemical oxygen demands from aqueous solutions and industrial wastewater.

The removal of heavy metal ions and organic materials from wastewater due to their toxicity is necessary. In the present study, the titanium dioxide/zinc oxide (TiO2 /ZnO) nanocomposite has been coated on the sewage sludge carbon (SSC) surface and its application was investigated for the adsorption of Ni(II), Cu(II), and chemical oxygen demands (COD) reduction from aqueous solutions and industrial wastewaters in Eshtehard, Iran. The effect of adsorption parameters in a single system such as TiO2 /ZnO ratio, TiO2 /ZnO concentration, pH, adsorbent dosage, contact time, ionic strength, temperature, and initial concentrations of Ni(II), Cu(II), and COD was investigated on the adsorption capacity of synthesized SSC/TiO2 /ZnO adsorbent. The pseudo-second order and Redlich-Peterson isotherm models were best described the kinetic and equilibrium data of Ni(II), Cu(II), and COD sorption. The maximum monolayer sorption capacities of Ni(II), Cu(II), and COD were found to be 62.3, 75.1, and 1,120.3 mg/g, respectively. The central composite design was used to investigate the interaction effects of pH and initial concentrations of Ni(II), Cu(II), and COD on the simultaneous removal of Ni(II), Cu(II), and COD from aqueous solutions in a ternary system. The potential of synthesized SSC/TiO2 /ZnO adsorbent was investigated for Ni(II), Cu(II), and COD adsorption from industrial wastewaters of Iran. PRACTITIONER POINTS: The novel sewage sludge carbon/TiO2 /ZnO adsorbent was synthesized. Adsorption of Ni(II), Cu(II), and chemical oxygen demands (COD) from industrial wastewaters was investigated. Maximum Ni(II), Cu(II), and COD sorption capacities were 62.3, 75.1, and 1,120.3 mg/g. Simultaneous removal of Ni(II), Cu(II), and COD was investigated in a ternary system.

Comprehensive analysis on sorptive uptake of enrofloxacin by activated carbon derived from industrial paper sludge.

The current investigation deals with how chemically activated carbon derived from industrial paper sludge (ACPS) performs on sorptive removal of enrofloxacin (ENF), an antibacterial drug from its water solution. Thermogravimetric (TGA) and proximate analysis of raw paper sludge (RPS) were conducted. ACPS was characterized with proximate analysis, XRD, FT-IR, SEM and BET. The influence of five operational parameters viz. adsorbate concentration (initial), dose of adsorbent, pH, temperature, and contact time on the adsorption of ENF onto ACPS has been conducted using batch experiments. The process of adsorption was optimized through ANN (artificial neural network) in addition to RSM (response surface methodology). The maximum percentage removal (95.85%) was achieved at initial ENF concentration 12 mg/g, adsorbent dose 1.2 g/L, contact duration of 18 h and temperature 20 °C. Kinetic data were best fitted into pseudo-second order kinetic model and adsorption equilibrium study indicates that the adsorption process follows Langmuir isotherm model. Adsorption capacity was noted to have a highest value of 44.44 mg/g. A study on thermodynamics of the adsorption process suggests that it exhibits spontaneity, being essentially exothermic. Cost analysis and reusability study confirm that adsorbent produced from industrial paper sludge is cost-effective and reusable. Therefore, ACPS as adsorbent has potency for removing ENF from aqueous solution.

Adsorption kinetics of colour removal from palm oil mill effluent using wastewater sludge carbon in column studies.

Treated palm oil mill effluents (POME) is of great concern as it still has colour from its dissolved organics which may pollute receiving water bodies. In this study, the removal of colour from treated palm oil mill effluent were investigated through adsorption studies using carbon derived from wastewater sludge (WSC). Sludge from activated sludge plants were dried and processed to produce WSC. In this study, three different bed depths of WSC were used: 5 cm, 10 cm, and 15 cm. For each bed depth, the flowrate was varied at three different values: 100 mL/hr, 50 mL/hr and 25 mL/hr. It was found that at bed depth of 5 cm, the breakthrough curves were occurred at 360 min, 150 min and 15 min for flowrates of 25, 50 and 100 mL/hr respectively. It was observed that at a particular depth the exhaustion time for column reduced as flow rate increases. Kinetic models, Adams-Bohart and Yoon-Nelson were used to analyze the performance of the adsorption. It was found that rate constant for Adams Bohart model decreased with the increase in bed depth. Adsorption capacity obtained from Adams-Bohart model ranged from 2676.19 mg/L up to 8938.78 mg/L. The maximum adsorption capacity increases with smaller bed depth. For Yoon-Nelson model, the rate constant decreases with increase in bed depth. The required time for 50% breakthrough obtained from the models ranged from 17.01 to 104.17 minutes for all three bed depths. The reduction of colour was found to be effective at all bed depths. The experimental data was best described by both models as with higher values of correlation coefficient (R2).

Nano-rod Ca-decorated sludge derived carbon for removal of phosphorus.

Recovering phosphorus (P) from waste streams takes the unique advantage in simultaneously addressing the crisis of eutrophication and the shortage of P resource. A novel calcium decorated sludge carbon (Ca-SC) was developed from dyeing industry wastewater treatment sludge by decorating calcium (Ca) to effectively adsorb phosphorus from solution. The X-ray diffraction (XRD) and Fourier transform infrared (FTIR) techniques were used to characterize the Ca-SCs, followed by isotherm and kinetic sorption experiments. A preferred design with CaCO3 to sludge mass ratio of 1:2 was found to have a sorption capacity of 116.82 mg/g for phosphorus. This work reveals the crucial role of well-dispersed nano-rod calcium on the Ca-SC surface for the sorption of phosphorus. Moreover, the decoration of nano-rod calcium was found to further promote the uptake of phosphorus through the formation of hydroxylapatite (Ca5(PO4)3(OH)). Thus, the development of decorated Ca-SC for sorption of phosphorus is very important in solving the P pollution and resource loss.

Tuning role and mechanism of paint sludge for characteristics of sewage sludge carbon: Paint sludge as a new macro-pores forming agent.

For the first time, paint sludge waste (PS) was used as a pore forming agent in the preparation of sewage sludge derived carbon (SC). The tuning role and mechanism of PS for characteristics of SC were explored. It was found that a sludge carbon (SCPS-Zn) with rich macro-, meso- and micro- porous could be produced by one-step pyrolytic process of sludge in the presence of PS and ZnCl2. Its surface area could reach as high as 680.5m2g-1 as 88.4 times and 4.8 times of sludge carbon without addition of PS and ZnCl2 (SC) and only addition of ZnCl2 (SCZn), respectively. The macro- pores fabricated by PS provided much inner-space for ZnCl2 to generate meso- and micro- porous, leading to a hierarchical porous structure. SCPS-Zn showed a high adsorption capacity of 685.4mgg-1 for Chrysophenine, which is 1.3 and 1.7 times that of SCPS and SCZn respectively. The adsorption difference could be simply attributed to the fact that the great molecules were difficult to enter micro- pores of SCZn. It was also found that the difference was also dependent on orientation of Chrysophenine, which was related to pH value of solution.

Potential enhancement of direct interspecies electron transfer for anaerobic degradation of coal gasification wastewater using up-flow anaerobic sludge blanket (UASB) with nitrogen doped sewage sludge carbon assisted.

Waste sewage sludge was converted into the novel conductive material of nitrogen doped sewage sludge carbon (N-SC) to enhance anaerobic degradation of coal gasification wastewater (CGW). The results indicated that N-SC played a significant role in enhanced efficiencies, with chemical oxygen demand (COD) removal efficiency increased by 25.4%, methane production rate improved by 68.1% and total volatile fatty acids (VFA) decreased by 37.5% than that of controlled reactor. The conductivity, activity of electron transport, and extracellular polymeric substances (EPS) of anaerobic sludge were remarkably enhanced with N-SC, which promoted sludge granulation and supplied better conductive environment for microorganisms. The microbial community analysis revealed that potential enhancement of direct interspecies electron transfer (DIET) was achieved by electrical connection between enriched Geobacter, Pseudomonas and Methanosaeta with N-SC assisted, which enhanced the anaerobic degradation of CGW. Moreover, anaerobic degradation with N-SC had higher capacity to resist acidic shocks, facilitating the process stability.

Effects of hydraulic retention time (HRT) on denitrification using waste activated sludge thermal hydrolysis liquid and acidogenic liquid as carbon sources.

Waste activated sludge (WAS) internal carbon source can efficiently and economically enhance denitrification, and hydraulic retention time (HRT) is one of the most important operational parameters for denitrification. The effects of HRT on denitrification were investigated with WAS thermal hydrolysis liquid and acidogenic liquid as carbon sources in this study. The optimal HRT was 12h for thermal hydrolysis liquid and 8h for acidogenic liquid, with NO3--N removal efficiency of 91.0% and 97.6%, respectively. In order to investigate the utilization of sludge carbon source by denitrifier, the changes of SCOD (Soluble chemical oxygen demand), proteins, carbohydrates, and VFAs (Volatile fatty acids) during denitrification process were analyzed and three-dimensional fluorescence excitation-emission matrix (EEM) spectroscopy with fluorescence regional integration (FRI) analysis was introduced. The kinetics parameters of denitrification rate (VDN), denitrification potential (PDN) and heterotroph anoxic yield (YH) were also investigated using sludge carbon source at different HRT.

Stepwise hydrolysis to improve carbon releasing efficiency from sludge.

Based on thermal alkaline hydrolysis (TAH), a novel strategy of stepwise hydrolysis was developed to improve carbon releasing efficiency from waste activated sludge (WAS). By stepwise increasing hydrolysis intensity, conventional sludge hydrolysis (the control) was divided into four stages for separately recovering sludge carbon sources with different bonding strengths, namely stage 1 (60 °C, pH 6.0-8.0), stage 2 (80 °C, pH 6.0-8.0), stage 3 (80 °C, pH 10.0) and stage 4 (90 °C, pH 12.0). Results indicate stepwise hydrolysis could enhance the amount of released soluble chemical oxygen demand (SCOD) for almost 2 times, from 7200 to 14,693 mg/L, and the released carbon presented better biodegradability, with BOD/COD of 0.47 and volatile fatty acids (VFAs) yield of 0.37 g VFAs/g SCOD via anaerobic fermentation. Moreover, stepwise hydrolysis also improved the dewaterability of hydrolyzed sludge, capillary suction time (CST) reducing from 2500 to 1600 s. Economic assessment indicates stepwise hydrolysis shows less alkali demand and lower thermal energy consumption than those of the control. Furthermore, results of this study help support the concepts of improving carbon recovery in wastewater by manipulating WAS composition and the idea of classifiably recovering the nutrients in WAS.