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This study presents an updated analysis spanning over two decades (1999-2023) of climate, water quality, and operational data from two drinking water facilities in Atlantic Canada that previously experienced gradual increases in the natural organic matter (NOM) concentration and brownification. The goal was to assess the impact of recent extreme weather events on acute NOM concentration increases and drinking water treatment processes. In 2023, a dry spring combined with a warm and wet summer caused NOM in the water supplies to increase by >67% (as measured by color). To mitigate increased NOM concentration, the alum dose nearly doubled in 2023 compared to that in 2022. Disinfection byproducts were elevated following the event but remained within the compliance levels. From 1999 to 2023, the two plants responded to gradual climate change impacts and brownification, with alum dose increases of between 4.1 and 8.3 times. Equivalent CO2 emissions were estimated for alum usage, which increased by 3 to 7-fold in 2023 compared to when the plants were commissioned decades prior. The plants were not only adversely impacted by climate change but also contributed to the global CO2 burden. Thus, a paradigm shift toward sustainable alternatives for NOM removal is required in the water sector, and climate change adaptation and mitigation principles are urgently needed.
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Mudança Climática , Água Potável , Purificação da Água , Água Potável/química , Abastecimento de Água , Qualidade da Água , CanadáRESUMO
2,6-Dichlorobenzamide (BAM) is an omnipresent micropollutant in European groundwaters. Aminobacter niigataensis MSH1 is a prime candidate for biologically treating BAM-contaminated groundwater since this organism is capable of utilizing BAM as a carbon and energy source. However, detailed information on the BAM degradation kinetics by MSH1 at trace concentrations is lacking, while this knowledge is required for predicting and optimizing the degradation process. Contaminating assimilable organic carbon (AOC) in media makes the biodegradation experiment a mixed-substrate assay and hampers exploration of pollutant degradation at trace concentrations. In this study, we examined how the BAM concentration affects MSH1 growth and BAM substrate utilization kinetics in a AOC-restricted background to avoid mixed-substrate conditions. Conventional Monod kinetic models were unable to predict kinetic parameters at low concentrations from kinetics determined at high concentrations. Growth yields on BAM were concentration-dependent and decreased substantially at trace concentrations; i.e., growth of MSH1 diminished until undetectable levels at BAM concentrations below 217 µg-C/L. Nevertheless, BAM degradation continued. Decreasing growth yields at lower BAM concentrations might relate to physiological adaptations to low substrate availability or decreased expression of downstream steps of the BAM catabolic pathway beyond 2,6-dichlorobenzoic acid (2,6-DCBA) that ultimately leads to Krebs cycle intermediates for growth and energy conservation.
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Benzamidas , Carbono , Phyllobacteriaceae , Biodegradação Ambiental , Benzamidas/metabolismo , Carbono/metabolismoRESUMO
In this study, pomegranate seed waste (PSW) was added into sand filter (SF) to increase removal efficiency of Lead (Pb(II)) and Copper (Cu(II)) from polluted water. The performance of PSW was compared with activated carbon (AC) as a typical adsorbent. Based on the SEM, EDX, FTIR, XRD, BET and proximate analyses, PSW had porous structure with specific surface area of 2.76 m2/g and active compounds which suggested PSW as an appropriate adsorbent for heavy metals (HMs) adsorption. According to the batch experiments, SF without treatment could only remove 46% and 35% of Pb(II) and Cu(II), respectively. These numbers increased to 88% and 75% for Pb(II) and Cu(II) by adding 3 g/kg PSW to the SF, respectively under the optimal conditions of HMs initial concentrations = 100 mg/L, pH = 7 and contact time = 60 min. The adsorption kinetic and isotherm followed the pseudo-first-order and Langmuir models, respectively indicating that mainly physisorption was involved in the HMs adsorption process of PSW. Based on the column experiments (flow rate = 62.5 mL/min), the Pb(II) and Cu(II) removal increased from 14% to 60% and 10%-55%, respectively after 5 pore volumes (40 min) by adding 3 g/kg PSW to the SF. Breakthrough curves matched better with Thomas mode rather than Adam's Bohart proving Langmuir adsorption isotherm. Our finding suggested modification of SF with PSW is a promising approach for efficient removal of HMs from water.
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The carbon peaking and carbon neutrality targets proposed by the Chinese government have initiated a green transformation that is full of challenges and opportunities and endowed sustainable development strategy for combating global warming issue. It is essential to execute comprehensive identification and carbon reduction measures across all industries that produce greenhouse gas (GHG) emissions. Water supply system, as an energy-intensive sector, plays a crucial role in GHG reduction. This work conducted a life cycle assessment (LCA) to account the GHG emissions associated with the construction and operation phases of the drinking water treatment plant (DWTP). During the construction phase, the total GHG emissions were 19,525.762 t CO2-eq, with concrete work and rebar project being the dominant contributors (87.712%). The promotion of renewable or recyclable green building materials and low-carbon construction methods, such as the utilization of prefabricated components and on-site assembly, holds significant importance in reducing GHG emissions during the construction phase of DWTP. Regarding the operation stage, the DWTP possessed an average annual GHG emission of 37,660.160 t CO2-eq and an average GHG intensity of 0.202 kg CO2-eq/m3. Most emissions were attributed to electricity consumption (67.388%), chemicals utilization (12.893%), and heat consumption (10.414%). By increasing the use of clean energy and implementing strict control measures in the water supply pumps, energy consumption and GHG emissions can be effectively reduced. This study offers valuable insights into the mapping of GHG emissions in the DWTP, facilitating the identification of key areas for targeted implementation of energy-saving and carbon-reducing measures.
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Água Potável , Gases de Efeito Estufa , Animais , Dióxido de Carbono/análise , Efeito Estufa , Carbono , Estágios do Ciclo de VidaRESUMO
The occurrence and removal of 38 antibiotics from nine classes in two drinking water treatment plants (WTPs) were monitored monthly over one year to evaluate the efficiency of typical treatment processes, track the source of antibiotics in tap water and assess their potential risks to ecosystem and human health. In both source waters, 18 antibiotics were detected at least once, with average total antibiotic concentrations of 538.5 ng/L in WTP1 and 569.3 ng/L in WTP2. The coagulation/flocculation and sedimentation, sand filtration and granular activated carbon processes demonstrated limited removal efficiencies. Chlorination, on the other hand, effectively eliminated antibiotics by 48.7 ± 11.9%. Interestingly, negative removal was observed along the distribution system, resulting in a significant antibiotic presence in tap water, with average concentrations of 131.5 ng/L in WTP1 and 362.8 ng/L in WTP2. Source tracking analysis indicates that most antibiotics in tap water may originate from distribution system. The presence of antibiotics in raw water and tap water posed risks to the aquatic ecosystem. Untreated or partially treated raw water could pose a medium risk to infants under six months. Water parameters, for example, temperature, total nitrogen and total organic carbon, can serve as indicators to estimate antibiotic occurrence and associated risks. Furthermore, machine learning models were developed that successfully predicted risk levels using water quality parameters. Our study provides valuable insights into the occurrence, removal and risk of antibiotics in urban WTPs, contributing to the broader understanding of antibiotic pollution in water treatment systems.
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Antibacterianos , Água Potável , Poluentes Químicos da Água , Purificação da Água , Água Potável/química , Purificação da Água/métodos , Antibacterianos/análise , Poluentes Químicos da Água/análise , Medição de Risco , HumanosRESUMO
Dissolved organic matter (DOM) is important in determining the drinking water treatment and the supplied water quality. However, a comprehensive DOM study for the whole water supply system is lacking and the potential effects of secondary water supply are largely unknown. This was studied using dissolved organic carbon (DOC), absorption spectroscopy, and fluorescence excitation-emission matrices-parallel factor analysis (EEM-PARAFAC). Four fluorescent components were identified, including humic-like C1-C2, tryptophan-like C3, and tyrosine-like C4. In the drinking water treatment plants, the advanced treatment using ozone and biological activated carbon (O3-BAC) was more effective in removing DOC than the conventional process, with the removals of C1 and C3 improved by 17.7%-25.1% and 19.2%-27.0%. The absorption coefficient and C1-C4 correlated significantly with DOC in water treatments, suggesting that absorption and fluorescence could effectively track the changes in bulk DOM. DOM generally remained stable in each drinking water distribution system, suggesting the importance of the treated water quality in determining that of the corresponding network. The optical indices changed notably between distribution networks of different treatment plants, which enabled the identification of changing water sources. A comparison of DOM in the direct and secondary water supplies suggested limited impacts of secondary water supply, although the changes in organic carbon and absorption indices were detected in some locations. These results have implications for better understanding the changes of DOM in the whole water supply system to help ensure the supplied water quality.
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Abastecimento de Água , Qualidade da Água , Purificação da Água/métodos , Substâncias Húmicas/análise , Água Potável/química , Água Potável/análise , Carbono/análiseRESUMO
As a byproduct of water treatment, drinking water treatment aluminum sludge (DWTAS) has challenges related to imperfect treatment and disposal, which has caused potential harm to human health and the environment. In this paper, heat treatment DWTAS as a supplement cementitious material was used to prepare a green cementing material. The results show that the 800°C is considered as the optimum heat treatment temperature for DWTAS. DWTAS-800°C is fully activated after thermal decomposition to form incompletely crystallized highly active γ-Al2O3 and active SiO2. The addition of DWTAS promoted the formation of ettringite and C-(A)-S-H gel, which could make up for the low early compressive strength of cementing materials to a certain extent. When cured for 90 days, the compressive strength of the mortar with 30% DWTAS-800°C reached 44.86 MPa. The dynamic process was well simulated by Krstulovic-Dabic hydration kinetics model. This study provided a methodology for the fabrication of environmentally friendly and cost-effective compound cementitious materials and proposed a "waste-to-resource" strategy for the sustainable management of typical solid wastes.
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Alumínio , Materiais de Construção , Esgotos , Alumínio/química , Cinética , Esgotos/química , Purificação da Água/métodos , Água Potável/química , Eliminação de Resíduos Líquidos/métodosRESUMO
Chlorine-based disinfection for drinking water treatment (DWT) was one of the 20th century's great public health achievements, as it substantially reduced the risk of acute microbial waterborne disease. However, today's chlorinated drinking water is not unambiguously safe; trace levels of regulated and unregulated disinfection byproducts (DBPs), and other known, unknown, and emerging contaminants (KUECs), present chronic risks that make them essential removal targets. Because conventional chemical-based DWT processes do little to remove DBPs or KUECs, alternative approaches are needed to minimize risks by removing DBP precursors and KUECs that are ubiquitous in water supplies. We present the "Minus Approach" as a toolbox of practices and technologies to mitigate KUECs and DBPs without compromising microbiological safety. The Minus Approach reduces problem-causing chemical addition treatment (i.e., the conventional "Plus Approach") by producing biologically stable water containing pathogens at levels having negligible human health risk and substantially lower concentrations of KUECs and DBPs. Aside from ozonation, the Minus Approach avoids primary chemical-based coagulants, disinfectants, and advanced oxidation processes. The Minus Approach focuses on bank filtration, biofiltration, adsorption, and membranes to biologically and physically remove DBP precursors, KUECs, and pathogens; consequently, water purveyors can use ultraviolet light at key locations in conjunction with smaller dosages of secondary chemical disinfectants to minimize microbial regrowth in distribution systems. We describe how the Minus Approach contrasts with the conventional Plus Approach, integrates with artificial intelligence, and can ultimately improve the sustainability performance of water treatment. Finally, we consider barriers to adoption of the Minus Approach.
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Desinfetantes , Água Potável , Poluentes Químicos da Água , Purificação da Água , Humanos , Inteligência Artificial , Poluentes Químicos da Água/análise , Desinfetantes/análise , Desinfecção , HalogenaçãoRESUMO
Access to safe drinking water is a major public concern in China. A national survey of 57â¯029 households was conducted to fill major knowledge gaps on drinking water sources, end-of-use treatment methods, and energy used to boil water. Herein, we show that surface water and well water were frequently used by >147 million rural residents living in low-income inland and mountainous areas. Driven by socioeconomic development and government intervention, the level of access to tap water in rural China increased to 70% by 2017. Nevertheless, the rate was considerably lower than that in cities and unevenly distributed across the country. Approximately 90% of drinking water was boiled, an increase from 85% a decade ago. The contribution of electricity, mainly electric kettles, to the boiling of water was 69%. Similar to cooking, living conditions and heating requirements are the main influencing indicators of energy used to boil water. In addition to socioeconomic development, government intervention is a key factor driving the transition to safe water sources, universal access to tap water, and clean energy. Further improvement in drinking water safety in poor and remote rural areas remains challenging, and more intervention and more investment are needed.
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Água Potável , Abastecimento de Água , Humanos , China , Cidades , Características da Família , População RuralRESUMO
High resolution mass spectrometry (HRMS) coupled to either gas chromatography or reversed-phase liquid chromatography is the generic method to identify unknown disinfection byproducts (DBPs) but can easily overlook their highly polar fractions. In this study, we applied an alternative chromatographic separation method, supercritical fluid chromatography-HRMS, to characterize DBPs in disinfected water. In total, 15 DBPs were tentatively identified for the first time as haloacetonitrilesulfonic acids, haloacetamidesulfonic acids, and haloacetaldehydesulfonic acids. Cysteine, glutathione, and p-phenolsulfonic acid were found as precursors during lab-scale chlorination, with cysteine providing the highest yield. A mixture of the labeled analogues of these DBPs was prepared by chlorination of 13C3-15N-cysteine and analyzed using nuclear magnetic resonance spectroscopy for structural confirmation and quantification. A total of 6 drinking water treatment plants utilizing various source waters and treatment trains produced sulfonated DBPs upon disinfection. Those were widespread in the tap water of 8 cities across Europe, with estimated concentrations up to 50 and 800 ng/L for total haloacetonitrilesulfonic acids and haloacetaldehydesulfonic acids, respectively. Up to 850 ng/L haloacetonitrilesulfonic acids were found in 3 public swimming pools. Considering the stronger toxicity of haloacetonitriles, haloacetamides, and haloacetaldehydes than the regulated DBPs, these newly found sulfonic acid derivatives may also pose a health risk.
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Cromatografia com Fluido Supercrítico , Desinfetantes , Água Potável , Poluentes Químicos da Água , Purificação da Água , Desinfecção/métodos , Desinfetantes/análise , Desinfetantes/química , Água Potável/análise , Ácidos Sulfônicos/análise , Cisteína/análise , Poluentes Químicos da Água/análise , Espectrometria de Massas , HalogenaçãoRESUMO
Over the past three decades, a notable rise in the occurrence of enteric protozoan pathogens, especially Giardia and Cryptosporidium spp., in drinking water sources has been observed. This rise could be attributed not only to an actual increase in water contamination but also to improvements in detection methods. These waterborne pathogens have played a pivotal role in disease outbreaks and the overall escalation of disease rates in both developed and developing nations worldwide. Consequently, the control of waterborne diseases has become a vital component of public health policies and a primary objective of drinking water treatment plants (DWTPs). Limited studies applied real-time PCR (qPCR) and/or immunofluorescence assay (IFA) for monitoring Giardia and Cryptosporidium spp., particularly in developing countries like Egypt. Water samples from two conventional drinking water treatment plants and two compact units (CUs) were analyzed using both IFA and qPCR methods to detect Giardia and Cryptosporidium. Using qPCR and IFA, the conventional DWTPs showed complete removal of Giardia and Cryptosporidium, whereas Mansheyat Alqanater and Niklah CUs achieved only partial removal. Specifically, Cryptosporidium gene copies removal rates were 33.33% and 60% for Mansheyat Alqanater and Niklah CUs, respectively. Niklah CU also removed 50% of Giardia gene copies, but no Giardia gene copies were removed by Mansheyat Alqanater CU. Using IFA, both Mansheyat Alqanater and Niklah CUs showed a similar removal rate of 50% for Giardia cysts. Additionally, Niklah CU achieved a 50% removal of Cryptosporidium oocysts, whereas Mansheyat Alqanater CU did not show any removal of Cryptosporidium oocysts. Conventional DWTPs were more effective than CUs in removing enteric protozoa. The contamination of drinking water by enteric pathogenic protozoa remains a significant issue globally, leading to increased disease rates. Infectious disease surveillance in drinking water is an important epidemiological tool to monitor the health of a population.
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Criptosporidiose , Cryptosporidium , Água Potável , Giardíase , Purificação da Água , Animais , Humanos , Giardia/genética , Cryptosporidium/genética , Criptosporidiose/epidemiologia , Criptosporidiose/prevenção & controle , Giardíase/epidemiologia , Giardíase/prevenção & controle , OocistosRESUMO
The presence of chironomid larvae in tap water has sparked public concern regarding the water supply system in South Korea. Despite ongoing efforts to establish a safe water supply system, entirely preventing larval occurrences remains a significant challenge. Therefore, we developed a real-time chironomid larva detection system (RT-CLAD) based on deep learning technology, which was implemented in drinking water treatment plants. The acquisition of larval images was facilitated by a multi-spectral camera with a wide spectral range, enabling the capture of unique wavelet bands associated with larvae. Three state-of-the-art deep learning algorithms, namely the convolutional neural network (CNN), you only look once (YOLO), and residual neural network (ResNet), renowned for their exceptional performance in object detection tasks, were employed. Following a comparative analysis of these algorithms, the most accurate and rapid model was selected for RT-CLAD. To achieve the efficient and accurate detection of larvae, the original images were transformed into a specific wavelet format, followed by preprocessing to minimize data size. Consequently, the CNN, YOLO, and ResNet algorithms successfully detected larvae with 100% accuracy. In comparison to YOLO and ResNet, the CNN algorithm demonstrated greater efficiency because of its faster processing and simpler architecture. We anticipate that our RT-CLAD will address larva detection challenges in water treatment plants, thereby enhancing water supply security.
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Chironomidae , Água Potável , Purificação da Água , Animais , Inteligência Artificial , LarvaRESUMO
The use of ceramsite to construct filtration systems (e.g., biofilters) is a common method for water treatment. To promote such applications, the development of low-cost, high-performance, and environmentally friendly ceramsites has received increasing attention from scientists, and a critical step in the development is the preparation of raw materials. As an inevitable and non-hazardous by-product during potable water production, drinking water treatment residue (DWTR) is typically recycled to make water treatment ceramsite to promote recycling in filtration systems. This study aims to bridge the knowledge gap regarding DWTR in making ceramsites for water treatment. The results suggest that the fabrication methods for DWTR-based ceramsite can be generally classified into sintering and non-sintering procedures. For the sintering method, owing to the heterogeneous properties (especially aluminum, iron, and calcium), DWTR has been applied as various sub-ingredients for raw materials preparations. In contrast, for the non-sintering method, DWTR is commonly applied as the main ingredient, and natural curing, physical crosslinking, and thermal treatment methods have been typically adopted to make ceramsite. However, DWTR-based ceramsites tend to have a high adsorption capability and favorable microbial effects to control different kinds of pollution (e.g., phosphorus, nitrogen, and organic matter). Future work is typically recommended to thoroughly evaluate the performance of DWTR-based ceramsite-constructed filtration systems to control water pollution concerning the making procedures, the potential to control pollution, the stability, and the safety of raw DWTR-based ceramsite, providing systematic information to design more proper planning for beneficial recycling.
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Água Potável , Purificação da Água , Ferro , Alumínio , Purificação da Água/métodosRESUMO
A data-driven Bayesian Network (BN) model was developed for a large Australian drinking water treatment plant, whose raw water comes from a river into which a number of upstream dams outflow water and smaller tributaries flow. During wet weather events, the spatial distribution of rainfall has a crucial role on the incoming raw water quality, as runoff from specific sub-catchments usually causes significant turbidity and conductivity issues, as opposed to larger dam outflows which have typically better water quality. The BN relies on a conceptual model developed following expert consultation, as well as a combination of different types (e.g. water quality, flow, rainfall) and amount (e.g. high-frequency, daily, scarce depending on variable) of historical data. The validated model proved to have acceptable accuracy in predicting the probability of different incoming raw water quality ranges, and can be used to assess different scenarios (e.g. timing, flow) of dam water releases, for the purpose of achieving dilution of the tributary's poor-quality water and mitigate related drinking water treatment challenges.
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Água Potável , Purificação da Água , Qualidade da Água , Teorema de Bayes , Austrália , Monitoramento AmbientalRESUMO
Drinking water treatment residues (DWTR) from mining areas which remove and contain potentially toxic elements (PTE) could still potentially be used as a soil amendment to restore contaminated sites in the same catchment, thus eliminating waste and reducing the chemical and physical mobility of the pollutants. To assess this restorative and regenerative approach to DWTR management, field and pot trials were established with soils from a historic Pb-Zn mine site in the North East of England, amended with either local DWTR or the nearest available municipal green waste compost (GWC). Soils from the mine site were found to have very low levels of nutrients and very high levels of PTE (Pb and Zn > 13, 000 mg/kg). The perennial grass species Phalaris arundinacea, known for many ecosystem service benefits including soil stabilization, was used throughout this study. The application of the BCR sequential extraction to soils amended with the DWTR in the pot trials found a significant decrease in the bioavailability of Pb and Cu (p < 0.05) after plant growth when compared with an unamended control. The field trial involved 648 pre-grown grass plants planted-out into mine soils amended with either DWTR, GWC or a mixture (MIX) of the two, all at rates of 25-30% w/w. Both amendments and the MIX had significant positive effects on biomass production compared to the unamended control in the following order GWC > MIX > DWTR (p < 0.05). Results of the elemental analysis of biomass from the field trial were generally ambiguous and did not reflect the decreased bioavailability noted in the pot trials using the BCR procedure. Pot trials, however, showed increases in plant growth and decreases in concentrations of Cr, Cu, Pb and Zn in above ground biomass following the application of both amendments. Further work should involve the testing of a mixture of DWTR and other soil amendments to enhance plant growth. The success of these trials should provide confidence for those working in drinking water treatment and catchment management to reuse the waste residues in a circular economy and a sustainable way that could improve water quality over time.
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Água Potável , Metais Pesados , Poluentes do Solo , Ecossistema , Chumbo , Poluentes do Solo/análise , Solo/química , Metais Pesados/químicaRESUMO
Antibiotic resistance in drinking water has received increasing attention in recent years. In this study, the occurrence and abundance of antibiotic resistance genes (ARGs) in a drinking water treatment plant (DWTP) was comprehensively investigated using metagenomics. Bioinformatics analysis showed that 381 ARG subtypes belonging to 15 ARG types were detected, and bacitracin had the highest abundance (from 0.26 × 10-2 to 0.86 copies/cell), followed by multidrug (from 0.57 × 10-1 to 0.47 copies/cell) and sulfonamide (from 0.83 × 10-2 to 0.35 copies/cell). Additionally, 933 ARG-carrying contigs (ACCs) were obtained from the metagenomic data, among which 153 contigs were annotated as pathogens. The most abundant putative ARG host was Staphylococcus (7.9%), which most frequently carried multidrug ARGs (43.2%). Additionally, 38 high-quality metagenome-assembled genomes (MAGs) were recovered, one of which was identified as Staphylococcus aureus (Bin.624) and harboured the largest number of ARGs (n = 16). Using the cultivation technique, 60 isolates were obtained from DWTP samples, and Staphylococcus spp. (n = 11) were found to be dominant in all isolates, followed by Bacillus spp. (n = 17). Antimicrobial susceptibility testing showed that most Staphylococcus spp. were multidrug resistant (MDR). These results deepen our understanding of the distribution profiles of ARGs and antibiotic resistant bacteria (ARB) in DWTPs for potential health risk evaluation. Our study also highlights the need for new and efficient water purification technologies that can be introduced and applied in DWTPs.
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Água Potável , Purificação da Água , Antibacterianos/farmacologia , Genes Bacterianos , Farmacorresistência Bacteriana/genética , Prevalência , Antagonistas de Receptores de Angiotensina , Inibidores da Enzima Conversora de Angiotensina , Purificação da Água/métodosRESUMO
In the present study, drinking water treatment sludge (DWTS) was reused as a catalyst in advanced oxidation processes for the removal of methylene blue (MB) from aqueous solutions. After determining their chemical and mineralogical compositions by X-ray Powder Diffraction (XRD), BET surface area, scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS), Inductively Coupled Plasma (ICP), and FT-IR spectra. DWTS has been used as a heterogeneous photo Fenton-Like catalyst for the oxidation of MB under different parameters, including pH (3-6), H2O2 concentration (9.79-29.37 mM), and dose (1-2.5 g/L). The results showed that within 180 min and under UV light irradiation, more than 86% of MB having a concentration of 50 mg/L were removed using a catalyst loading of 1.5 g/L, a H2O2 dosage of 23.17 mM and a solution pH of 5. The DWTS has a satisfactory stability as the catalyst is stable and have very less iron leaching property.
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Água Potável , Poluentes Químicos da Água , Esgotos , Azul de Metileno , Peróxido de Hidrogênio/química , Espectroscopia de Infravermelho com Transformada de Fourier , Adsorção , Catálise , Poluentes Químicos da Água/químicaRESUMO
Third-party certification to drinking water product consensus standards is how products for potable water systems are deemed suitable for public health and safety in North America. Drinking water product consensus standards are a type of standard developed through a process that includes participation from expert volunteers and requires general agreement from all stakeholders. Certification to drinking water product consensus standards is required via plumbing codes and state or local regulations in most of the United States and Canada, making third-party certification essential for products intended for sale and installation in North America. Third-party certification bodies (CBs) test and certify products to these drinking water product consensus standards through an evaluation process that includes a thorough review of each product's composition, laboratory testing, and inspection of each facility where the product is manufactured. Products that comply with the consensus standard requirements are entitled to bear a certification mark that demonstrates their suitability for use in potable water systems. Drinking water product standards developed by NSF reference NSF/ANSI/CAN 600: Health Effects Evaluation and Criteria for Chemicals in Drinking Water for the toxicological criteria to evaluate chemical leachates derived from material extraction testing. Here, we review the third-party product certification process for evaluating products used in potable water systems and describe how the certification process relies on the health effects criteria and toxicological evaluation procedures described in NSF/ANSI/CAN 600.
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A conventional evaluation methodology for drinking water pollution focuses on analysing hundreds of compounds, usually by liquid chromatography-tandem mass spectrometry. High-resolution mass spectrometry allows comprehensive evaluation of all detected signals (compounds) based on their elemental composition, intensity, and numbers. We combined target analysis of 192 emerging micropollutants with nontarget (NT) full-scan/MS/MS methods to describe the impact of treatment steps in detail and assess drinking water treatment efficiency without compound identification. The removal efficiency based on target analytes ranged from - 143 to 97%, depending on the treatment section, technologies, and season. The same effect calculated for all signals detected in raw water by the NT method ranged between 19 and 65%. Ozonation increased the removal of micropollutants from the raw water but simultaneously caused the formation of new compounds. Moreover, ozonation byproducts showed higher persistence than products formed during other types of treatment. We evaluated chlorinated and brominated organics detected by specific isotopic patterns within the developed workflow. These compounds indicated anthropogenic raw water pollution but also potential treatment byproducts. We could match some of these compounds with libraries available in the software. We can conclude that passive sampling combined with nontargeted analysis shows to be a promising approach for water treatment control, especially for long-term monitoring of changes in technology lines because passive sampling dramatically reduces the number of samples and provides time-weighted average information for 2 to 4 weeks.
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Água Potável , Ozônio , Poluentes Químicos da Água , Purificação da Água , Espectrometria de Massas em Tandem/métodos , Água Potável/análise , Monitoramento Ambiental/métodos , Poluentes Químicos da Água/análise , Purificação da Água/métodos , Ozônio/análiseRESUMO
Bioaugmentation often involves an invasion process requiring the establishment and activity of a foreign microbe in the resident community of the target environment. Interactions with resident micro-organisms, either antagonistic or cooperative, are believed to impact invasion. However, few studies have examined the variability of interactions between an invader and resident species of its target environment, and none of them considered a bioremediation context. Aminobacter sp. MSH1 mineralizing the groundwater micropollutant 2,6-dichlorobenzamide (BAM), is proposed for bioaugmentation of sand filters used in drinking water production to avert BAM contamination. We examined the nature of the interactions between MSH1 and 13 sand filter resident bacteria in dual and triple species assemblies in sand microcosms. The residents affected MSH1-mediated BAM mineralization without always impacting MSH1 cell densities, indicating effects on cell physiology rather than on cell number. Exploitative competition explained most of the effects (70%), but indications of interference competition were also found. Two residents improved BAM mineralization in dual species assemblies, apparently in a mutual cooperation, and overruled negative effects by others in triple species systems. The results suggest that sand filter communities contain species that increase MSH1 fitness. This opens doors for assisting bioaugmentation through co-inoculation with "helper" bacteria originating from and adapted to the target environment.