Semi-Coherent Heterointerface Engineering via In Situ Phase Transition for Enhanced Sodium/Lithium-Ions Storage.

To improve ion transport kinetics and electronic conductivity between the different phases in sodium/lithium-ion battery (LIB/SIB) anodes, heterointerface engineering is considered as a promising strategy due to the strong built-in electric field. However, the lattice mismatch and defects in the interphase structure can lead to large grain boundary resistance, reducing the ion transport kinetics and electronic conductivity. Herein, monometallic selenide Fe3Se4-Fe7Se8 semi-coherent heterointerface embedded in 3D connected Nitrogen-doped carbon yolk-shell matrix (Fe3Se4-Fe7Se8@NC) is obtained via an in situ phase transition process. Such semi-coherent heterointerface between Fe3Se4 and Fe7Se8 shows the matched interfacial lattice and strong built-in electric field, resulting in the low interface impedance and fast reaction kinetics. Moreover, the yolk-shell structure is designed to confine all monometallic selenide Fe3Se4-Fe7Se8 semi-coherent heterointerface nanoparticles, improving the structural stability and inhibiting the volume expansion effect. In particular, the 3D carbon bridge between multi-yolks shell structure improves the electronic conductivity and shortens the ion transport path. Therefore, the efficient reversible pseudocapacitance and electrochemical conversion reaction are enabled by the Fe3Se4-Fe7Se8@NC, leading to the high specific capacity of 439 mAh g-1 for SIB and 1010 mAh g-1 for LIB. This work provides a new strategy for constructing heterointerface of the anode for secondary batteries.

Hierarchical multi-yolk-shell copper oxide@copper-1, 3, 5-benzenetricarboxylate as an ultrastable anode for lithium ion batteries.

The capacity attenuation of transition metal oxides (TMOs) and metal-organic frameworks (MOFs) is the obstacle for practical application in lithium ion batteries, due to the extensive volume variation upon charge/discharge cycles. Herein, a hierarchical composite material with copper oxide (CuO) multi-yolks and copper-1, 3, 5-benzenetricarboxylate (Cu-BTC) shell is synthesized by a facile method to study the effect of the hierarchical structure on the electrochemical performance. The porosity and pore volume of CuO@Cu-BTC composites are optimized to buffer the volume change and facilitate the infiltration of electrolytes by altering reaction conditions. The CuO@Cu-BTC (20 h) with the largest surface area and pore volume delivers an excellent reversible capacity of 780.7 mAh g-1 at 200 mA g-1 after 100 cycles, and ultrastable long-term performance with a specific capacity of 569 mAh g-1 at a current density of 1000 mA g-1 after 900 cycles. The corresponding full battery shows moderate capacity retention from 149.4 to 125.8 mAh g-1 after 70 cycles, with a specific capacity retention of 84.2%, based on the mass of lithium iron phosphate (LiFePO4) at 0.2 C (1 C = 170 mA g-1). This strategy applies copper oxide as the metal source of the coordination compound, as well as the internal yolks, which can be extended to the in-situ construction of other hierarchical composites, providing a new avenue for practical application of TMOs and MOFs as anode materials.

A Partial Sulfuration Strategy Derived Multi-Yolk-Shell Structure for Ultra-Stable K/Na/Li-ion Storage.

Metal sulfides are attractive anodes for alkali metal ion batteries due to the high theoretical capacity, while their practical implementation is hampered by the inherent poor conductivity and vast volume variation during cycles. Approaching rational designed microstructures with good stability and fast charge transfer is of great importance in response to these issues. Herein, a partial sulfuration strategy for the rational construction of multi-yolk-shell (m-Y-S) structures, from which multiple Fe1- x S nanoparticles are confined within hollow carbon nanosheet with tunable interior void space is reported. As anode materials, the m-Y-S Fe1- x S@C composite can display high capacity and excellent rate capability (134, 365, and 447 mA h g-1 for K+ , Na+ , and Li+ storage at 20 A g-1 ). Remarkably, it exhibits ultra-stable potassium storage up to 1200, 6000, and 20 000 cycles under current densities of 0.1, 0.5, and 1 A g-1 , which is much superior to previous yolk-shell structures and metal-sulfide anodes. Based on comprehensive experimental analysis and theoretical calculations, the exceptional performance of m-Y-S structure can be ascribed to the optimized interior void space for good structure stability, as well as the multiple connection points and conductive carbon layer for superior electron/ion transportation.