[Raman and infrared spectral studies of tungsten organometallic carbyne complex at high external pressure].
Guang Pu Xue Yu Guang Pu Fen Xi
; 21(5): 596-8, 2001 Oct.
Article
em Zh
| MEDLINE
| ID: mdl-12945305
ABSTRACT
The Raman and infrared spectra of complex [Cl(CO)2 (DPPE) W identical to CC6H4C identical to CC6H4NC]2 Re Cl(CO)3 (DPPE = bis (diphenylphosphino) ethane, (Ph)2PCH2CH2P(Ph)2) were measured at high external pressure (up to about 50 kbar). The pressure induced phase transition was observed near 30 kbar. The pressure dependence d nu/dp of nu (W identical to C) at the low-pressure phase is a little high (0.59 cm-1.(kbar)-1) and is very low (0.04 cm-1.(kbar)-1) at the high-pressure phase. It shows that the pi-backbonding from W to pi*--orbital of CO is strengthened at the high external pressure in fragment Cl(CO)2 (DPPE) W identical to C; The bond intensity and the force constant of W identical to C and nu (W identical to C) are decreasing; This effect compete with the normal increasing nu (W identical to C) on compression.
Buscar no Google
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Tungstênio
/
Carbamatos
Idioma:
Zh
Revista:
Guang Pu Xue Yu Guang Pu Fen Xi
Ano de publicação:
2001
Tipo de documento:
Article
País de afiliação:
China