Enantioselective conjugate radical addition to alpha'-hydroxy enones.
Org Lett
; 8(19): 4311-3, 2006 Sep 14.
Article
em En
| MEDLINE
| ID: mdl-16956214
ABSTRACT
Enantioselective conjugate radical addition to alpha'-hydroxy alpha,beta-unsaturated ketones, compounds containing bidentate donors, has been investigated. It has been found that radical additions to alpha'-hydroxy alpha,beta-unsaturated ketones in the presence of Mg(NTf2)2 and bisoxazoline ligand 5a proceeded cleanly, yielding the addition products in high chemical yields and good enantiomeric excesses.
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Base de dados:
MEDLINE
Assunto principal:
Cetonas
Idioma:
En
Revista:
Org Lett
Assunto da revista:
BIOQUIMICA
Ano de publicação:
2006
Tipo de documento:
Article