Synthesis of indenyl ethers by gold(I)-catalyzed intramolecular carboalkoxylation of alkynes.
J Am Chem Soc
; 128(37): 12062-3, 2006 Sep 20.
Article
em En
| MEDLINE
| ID: mdl-16967944
ABSTRACT
The gold(I)-catalyzed carboalkoxylation of alkynes to form indanone derivatives from readily available ortho-acetylenic benzylic ethers is described. Importantly, the gold(I)-catalyzed rearrangement of enantioenriched benzylic ethers proceeds with chirality transfer, thus providing a practical method for the enantioselective synthesis of indenyl ethers.
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Base de dados:
MEDLINE
Assunto principal:
Compostos de Benzilideno
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Alcinos
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Éteres
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Indenos
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2006
Tipo de documento:
Article
País de afiliação:
Estados Unidos