Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions.

Meeuwissen, Jurjen; Detz, Remko J; Sandee, Albertus J; de Bruin, Bas; Reek, Joost N H

Meeuwissen, Jurjen; Detz, Remko J; Sandee, Albertus J; de Bruin, Bas; Reek, Joost N H.

Afiliação

Meeuwissen J; Homogeneous and Supramolecular Catalysis, Van't Hoff Institute for Molecular Sciences, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands.

Dalton Trans ; 39(8): 1929-31, 2010 Feb 28.

Article em En | MEDLINE | ID: mdl-20148206

RESUMO

We present new ureaphosphine ligands that coordinate in a P,O-bidentate fashion to rhodium(i). The ureaphosphine-Rh(i)-complexes were effectively used in the asymmetric hydrogenation of cyclic enamides giving high conversions and enantioselectivity.

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2010 Tipo de documento: Article País de afiliação: Holanda

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