Incorporation of arene metal carbonyl complexes within inorganic-organic hybrid mesoporous materials by CVD method.
J Nanosci Nanotechnol
; 10(1): 314-8, 2010 Jan.
Article
em En
| MEDLINE
| ID: mdl-20352853
ABSTRACT
Simple chemical vapor deposition (CVD) of M(CO), (M = Cr, Mo, W) onto phenylene- and biphenylene-bridged organosilica mesoporous materials (HMM-ph, HMM-biph) led to the efficient formation of C6H4M(CO)3 and (C6H4)2M(CO)3 complexes, respectively, which are directly fixed and incorporated within the framework structure of HMM-ph and HMM-biph having molecular-scale periodicity in the pore walls. FT-IR investigations revealed that thus formed C6H4M(CO), or (C6H4)2M(CO)3 complexes are thermally stable even under thermovacuum treatment at 473 K.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
J Nanosci Nanotechnol
Ano de publicação:
2010
Tipo de documento:
Article
País de afiliação:
Japão