Combined experimental and theoretical investigation of three-dimensional, nitrogen-doped, gallium cluster anions.
J Phys Chem A
; 114(42): 11070-7, 2010 Oct 28.
Article
em En
| MEDLINE
| ID: mdl-20373798
ABSTRACT
Anion photoelectron spectra of Ga(x)N(y)(-) cluster anions, in which x = 4-12, y = 1 and x = 7-12, y = 2, were measured. Ab initio studies were conducted on Ga(x)N(y)(-) cluster anions in which x = 4-7, y = 1 and Ga(7)N(2)(-), providing their structures and electronic properties. The photoelectron spectra were interpreted in terms of the computational results. This allowed for identification of the isomers present in the beam experiments for specific Ga(x)N(-) cluster anions (x = 4-7). The unexpected presence of Ga(x)N(2)(-) species is also reported.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
J Phys Chem A
Assunto da revista:
QUIMICA
Ano de publicação:
2010
Tipo de documento:
Article
País de afiliação:
Estados Unidos