Microwave-assisted pretreatment of recalcitrant softwood in aqueous glycerol.
Bioresour Technol
; 101(23): 9355-60, 2010 Dec.
Article
em En
| MEDLINE
| ID: mdl-20678924
ABSTRACT
Microwave-assisted pretreatment of recalcitrant softwood in aqueous glycerol containing a series of organic and inorganic acids with different pK(a) values was examined. The pulp obtained by organosolvolysis with 0.1% hydrochloric acid (pK(a) -6) at 180 degrees C for 6 min gave the highest sugar yield, 53.1%, based on the weight of original biomass. The pretreatment efficiency correlated linearly with the pK(a) of the acids, with the exception of malonic and phosphoric acids. Organosolvolysis with 1.0% phosphoric acid (pK(a) 2.15) gave a saccharification yield (50.6%) higher than that expected from its pK(a), while the catalytic effect of malonic acid (pK(a) 2.83) was negligible. Extensive exposure of crystalline and non-crystalline cellulose by the glycerolysis with strong inorganic acids was demonstrated by using fluorescent-labeled recombinant carbohydrate-binding modules (CBMs). Because of the low concentration of the acid catalysts and availability of glycerol as a by-product from biodiesel and fatty acid production, organosolvolysis in glycerol is an appealing process for pretreatment of recalcitrant softwood.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Madeira
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Água
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Cedrus
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Glicerol
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Micro-Ondas
Idioma:
En
Revista:
Bioresour Technol
Assunto da revista:
ENGENHARIA BIOMEDICA
Ano de publicação:
2010
Tipo de documento:
Article
País de afiliação:
Japão