Functionalization of selectively grown networked SnO2 nanowires with Pd nanodots by γ-ray radiolysis.

ABSTRACT

γ-ray radiolysis is applied to synthesizing Pd nanodots on networked SnO(2) nanowires. The growth behavior of Pd nanodots is systematically investigated as a function of the precursor concentration, illumination intensity, and exposure time of the γ-rays. These factors greatly influence the growth behavior of the Pd nanodots. Selectively grown networked SnO(2) nanowires are uniformly functionalized with Pd nanodots by the radiolysis process. The NO(2) sensing characteristics of the Pd-functionalized SnO(2) nanowires are compared with those of bare SnO(2) nanowires. The results indicate that γ-ray radiolysis is an attractive means of functionalizing the surface of oxide nanowires with catalytic Pd nanodots. Moreover, the Pd-functionalization greatly enhances the sensitivity and response time in SnO(2) nanowire-based gas sensors.