Nuclearity control of a trisaloph zinc cluster complex dependent on minute structural differences in the bridging anions.
Inorg Chem
; 50(12): 5315-7, 2011 Jun 20.
Article
em En
| MEDLINE
| ID: mdl-21568274
ABSTRACT
The Zn(6) cluster complex 2 of the trisaloph ligand was synthesized using EtCO(2)(-) anions as bridging ligands. Complex 2 has a dimeric structure in the crystalline state, while two monomeric isomers were in equilibrium in solution. The anion-exchange reaction successfully resulted in nuclearity control from Zn(7) to Zn(6).
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2011
Tipo de documento:
Article
País de afiliação:
Japão