10-Methyl-9-phenoxy-carbonyl-acridinium trifluoro-methane-sulfonate monohydrate.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 4): o906-7, 2010 Mar 24.
Article
em En
| MEDLINE
| ID: mdl-21580718
ABSTRACT
In the crystal structure of the title compound, C(21)H(16)NO(2) (+)·CF(3)SO(3) (-)·H(2)O, the anions and the water mol-ecules are linked by O-Hâ¯O inter-actions, while the cations form inversion dimers through π-π inter-actions between acridine ring systems. These dimers are linked by C-Hâ¯O and C-Fâ¯π inter-actions to adjacent anions, and by C-Hâ¯π inter-actions to neighboring cations. The water mol-ecule links two H atoms of the cation by C-Hâ¯O inter-actions and two adjacent anions by O-Hâ¯O inter-actions. The acridine and benzene ring systems are oriented at 15.6â
(1)°. The carboxyl group is twisted at an angle of 77.0â
(1)° relative to the acridine skeleton. The mean planes of the adjacent acridine units are either parallel or inclined at an angle of 18.4â
(1)°.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2010
Tipo de documento:
Article
País de afiliação:
Polônia