catena-Poly[[diaqua-(1,10-phenanthroline-κN,N')nickel(II)]-µ-1H-benzimidazole-5,6-dicarboxyl-ato-κN:O].
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 6): m701, 2009 May 29.
Article
em En
| MEDLINE
| ID: mdl-21583055
ABSTRACT
In the title complex, [Ni(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is hexa-coordinated by one N and one O atom from two different 1H-benzimidazole-5,6-dicarboxyl-ate ligands, two N atoms from one 1,10-phenanthroline ligand and two water mol-ecules. The flexible 1H-benzimidazole-5,6-dicarboxyl-ate ligands link the Ni(II) centres, forming an infinite zigzag chain parallel to [001]. The crystal packing is governed by inter-molecular hydrogen-bonding inter-actions of the O-Hâ¯O, N-Hâ¯O and C-Hâ¯O types.
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MEDLINE
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En
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Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2009
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Article