Aerobic oxidative kinetic resolution of secondary alcohols with naphthoxide-bound iron(salan) complex.
J Am Chem Soc
; 133(33): 12937-9, 2011 Aug 24.
Article
em En
| MEDLINE
| ID: mdl-21780821
ABSTRACT
The first general method for iron-catalyzed aerobic oxidative kinetic resolution of secondary alcohols was achieved with good to high enantiomeric differentiation (k(rel) = 7-50). Although iron(salan) complex 1 does not catalyze alcohol oxidation, the naphthoxide-bound iron(salan) complex does.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2011
Tipo de documento:
Article
País de afiliação:
Japão