Electrocatalytic oxidation of alcohols by a carbon-supported Rh porphyrin.

Yamazaki, Shin-ichi; Yao, Masaru; Fujiwara, Naoko; Siroma, Zyun; Yasuda, Kazuaki; Ioroi, Tsutomu

Yamazaki, Shin-ichi; Yao, Masaru; Fujiwara, Naoko; Siroma, Zyun; Yasuda, Kazuaki; Ioroi, Tsutomu.

Afiliação

Yamazaki S; Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology, 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan. s-yamazaki@aist.go.jp

Chem Commun (Camb) ; 48(36): 4353-5, 2012 May 07.

Article em En | MEDLINE | ID: mdl-22450541

ABSTRACT

ABSTRACT

A Rh porphyrin on carbon black was shown to catalyze the electro-oxidation of several aliphatic alcohols (ethanol, 1-propanol, and 2-propanol) and benzyl alcohols. The overpotentials for alcohol oxidation were very low. The reaction mechanism and substrate specificity are discussed.

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2012 Tipo de documento: Article País de afiliação: Japão

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