Aqua-[6-carboxyl-ato-N'-(pyridin-2-yl-methyl-idene)pyridine-2-carbohydrazidato]copper(II) trihydrate.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 6): m783, 2012 Jun 01.
Article
em En
| MEDLINE
| ID: mdl-22719334
In the title compound, [Cu(C(13)H(8)N(4)O(3))(H(2)O)]·3H(2)O, the complex molecule, except for the aqua ligand, is essentially planar [r.m.s. deviation = 0.034â
(2)â
Å]. The coordination polyhedron of the Cu(2+) cation is a square-pyramid, with the aqua ligand at the apex. The compound exhibits a three-dimensional structure, which is is stabilized by O-Hâ¯O and O--Hâ¯N hydrogen bonds and π-π inter-actions [centroid-centroid distance = 2.987â
(3)â
Å].
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Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2012
Tipo de documento:
Article