(Z)-3-(2-Hy-droxy-eth-yl)-2-(phenyl-imino)-1,3-thia-zolidin-4-one.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 8): o2371-2, 2012 Aug 01.
Article
em En
| MEDLINE
| ID: mdl-22904835
In the title compound, C(11)H(12)N(2)O(2)S, the thia-zole and phenyl rings are inclined at 56.99â
(6)° to one another. The thia-zole ring is planar with an r.m.s. deviation for the five ring atoms of 0.0274â
Å. The presence of the phenyl-imine substituent is confirmed with the C=N distance to the thia-zole ring of 1.2638â
(19)â
Å. The mol-ecule adopts a Z conformation with respect to this bond. The -OH group of the hy-droxy-ethyl substituent is disordered over two positions with relative occupancies 0.517â
(4) and 0.483â
(4). In the crystal, O-Hâ¯O hydrogen bonds, augmented by C-Hâ¯N contacts, form dimers with R(2) (2)(11) rings and generate chains along the b axis. Parallel chains are linked in an obverse fashion by weak C-Hâ¯S hydrogen bonds. C-Hâ¯O hydrogen bonds together with C-Hâ¯π contacts further consolidate the structure, stacking mol-ecules along the b axis.
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MEDLINE
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En
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Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2012
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Article