The Jahn-Teller effect in the electron momentum spectroscopy of ammonia.
J Chem Phys
; 137(17): 174305, 2012 Nov 07.
Article
em En
| MEDLINE
| ID: mdl-23145729
ABSTRACT
The 1e and 3a(1) bands of the ammonia molecule have been studied using the high-resolution electron momentum spectroscopy at impact energies of 1200 and 600 eV. Several slices of 1e and 3a(1) bands in the different binding energy ranges were selected, and their electron-momentum distributions were carefully compared. The discernable difference among the distributions of the selected slices of the 1e band shows that the Jahn-Teller effect indeed influences the electron momentum distribution of the 1e orbital of ammonia.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
J Chem Phys
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
China