2-Ethyl-3-hy-droxy-1-isopropyl-4-pyridone.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 11): o3235-6, 2012 Nov 01.
Article
em En
| MEDLINE
| ID: mdl-23284535
The title compound, C(10)H(15)NO(2), crystallized with three mol-ecules in the asymmetric unit. These three mol-ecules are quite similar except for slight differences in the torsion angles of the substituents on the ring. The isopropyl C-C-N-C torsion angles (towards the carbon next to the ethyl bound carbon), for example, are -150.63â
(11), -126.77â
(13) and -138.76â
(11)° for mol-ecules A, B and C, respectively, and the C-C-C-N torsion angles involving the ethyl C atoms are 102.90â
(13), 87.81â
(14) and 86.47â
(13)°. The main difference between the three mol-ecules lies in the way they are arranged in the solid-state structure. All three mol-ecules form dimers that are connected through strong O-Hâ¯O hydrogen bonds with R(2) (2)(10) graph-set motifs. The symmetry of the dimers formed does however differ between mol-ecules. Mol-ecules B connect with each other to form inversion dimers. Mol-ecules A and C, on the other hand, form dimers with local twofold symmetry, but the two mol-ecules are crystallographically distinct. The B and C molecules are linked to themselves and to each other via C-Hâ¯O hydrogen bonds. This results in the formation of a three-dimensional network structure.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
África do Sul