Bis(4,4'-sulfanediyldipyridinium) tetra-chloridonickelate(II) dichloride.
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 1): m59, 2013 Jan 01.
Article
em En
| MEDLINE
| ID: mdl-23476352
ABSTRACT
In the title compound, (C10H10N2S)2[NiCl4]Cl2, the Ni(2+) cation is tetra-hedrally coordinated by four chloride anions. Two 4,4'-sulfanediyldipyridinium cations and two non-coordinating chloride anions are connected via N-Hâ¯Cl hydrogen-bonding inter-actions into 20-membered rings, in the middle of which are situated the [NiCl4](2-) complex anions. These rings are stacked in the b-axis direction. The Ni(2+) cation is located on a twofold rotation axis, whereas the chloride anions and the 4,4'-sulfanediyldipyridinium cations occupy general positions.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
Alemanha