The coordination chemistry of tartronic acid with copper: magnetic studies of a quasi-equilateral tricopper triangle.
Dalton Trans
; 43(2): 656-62, 2014 Jan 14.
Article
em En
| MEDLINE
| ID: mdl-24135913
ABSTRACT
The coordination chemistry of tartronic acid, , with copper(ii) has been investigated. Structures of two complexes are reported containing respectively the complex [Cu(-2H)2Cl](3-) where acts as a bidentate ligand through carboxylates, and [Cu3(-3H)3](3-) where the alcohol function is deprotonated to bridge two coppers in a triangular trinuclear complex. The latter species undergoes facile oxidation leading to carbon-carbon bond formation. The magnetic and EPR properties of the trinuclear complex have been studied in detail.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2014
Tipo de documento:
Article
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