A mixed molecular building block strategy for the design of nested polyhedron metal-organic frameworks.
Angew Chem Int Ed Engl
; 53(3): 837-41, 2014 Jan 13.
Article
em En
| MEDLINE
| ID: mdl-24282117
ABSTRACT
A mixed molecular building block (MBB) strategy for the synthesis of double-walled cage-based porous metal-organic frameworks (MOFs) is presented. By means of this method, two isostructural porous MOFs built from unprecedented double-walled metal-organic octahedron were obtained by introducing two size-matching C3 -symmetric molecular building blocks with different rigidities. With their unique framework structures, these MOFs provide, to the best of our knowledge, the first examples of double-walled octahedron-based MOFs.
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MEDLINE
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En
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Angew Chem Int Ed Engl
Ano de publicação:
2014
Tipo de documento:
Article