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Shear propagation in the terahertz dynamics of water-glycerol mixtures.
Cunsolo, Alessandro; Kodituwakku, Chaminda N; Bencivenga, Filippo; Said, Ayman H.
Afiliação
  • Cunsolo A; Brookhaven National Laboratory, Photon Sciences Division, P.O. Box 5000, Upton, New York 11973, USA.
J Chem Phys ; 139(18): 184507, 2013 Nov 14.
Article em En | MEDLINE | ID: mdl-24320284
Inelastic X-ray and neutron scattering techniques were jointly used to investigate the dynamics of water-glycerol mixtures at different concentrations and temperatures. It was observed that even relatively low concentrations of glycerol increase the damping of shear modes, as a consequence of the known ability of glycerol to disrupt the hydrogen bond network of water. A similar trend was observed when increasing the temperature, which suggests the presence of a locus in the concentration-temperature plane marking a crossover in the shear modulus.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Chem Phys Ano de publicação: 2013 Tipo de documento: Article País de afiliação: Estados Unidos

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Chem Phys Ano de publicação: 2013 Tipo de documento: Article País de afiliação: Estados Unidos