Taming the carboxyl group for directed carbometalation: observations on the use of anions, dianions and ester enolates.
Chemistry
; 20(29): 8918-22, 2014 Jul 14.
Article
em En
| MEDLINE
| ID: mdl-24961599
ABSTRACT
Carboxylate anions, dianions and ester enolates provide simultaneous protection and activation for directed carbometalation reactions. Advantage can be taken of the bis-carbanionic character of the intermediate for further controlled C-C bond forming reactions.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Chemistry
Assunto da revista:
QUIMICA
Ano de publicação:
2014
Tipo de documento:
Article