Reaction dynamics at liquid interfaces.
Annu Rev Phys Chem
; 66: 165-88, 2015 Apr.
Article
em En
| MEDLINE
| ID: mdl-25493713
ABSTRACT
The liquid interface is a narrow, highly anisotropic region, characterized by rapidly varying density, polarity, and molecular structure. I review several aspects of interfacial solvation and show how these affect reactivity at liquid/liquid interfaces. I specifically consider ion transfer, electron transfer, and SN2 reactions, showing that solvent effects on these reactions can be understood by examining the unique structure and dynamics of the liquid interface region.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Annu Rev Phys Chem
Ano de publicação:
2015
Tipo de documento:
Article