Synthesis and characterization of [Fe(BPMEN)ACC]SbF6: a structural and functional mimic of ACC-oxidase.
Dalton Trans
; 44(13): 5966-8, 2015 Apr 07.
Article
em En
| MEDLINE
| ID: mdl-25734403
ABSTRACT
A mononuclear Fe(II) complex bearing 1-aminocyclopropane-1-carboxylic acid (ACCH) was synthesized and characterized. X-ray crystallography demonstrated that ACC binds to the Fe(II) ion in a bidentate mode constituting the first structural mimic of the expected binding of ACC to the Fe(II) center of the ethylene forming enzyme ACC-oxidase (ACCO). [Fe(BPMEN)ACC]SbF6 also constitutes a functional biomimetic complex of ACCO, as it reacts with hydrogen peroxide producing ethylene.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Compostos Ferrosos
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Materiais Biomiméticos
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Complexos de Coordenação
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Aminoácido Oxirredutases
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Aminoácidos Cíclicos
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2015
Tipo de documento:
Article
País de afiliação:
França