Ir-Catalyzed enantioselective group transfer reactions.
Chem Soc Rev
; 44(17): 5969-80, 2015 Oct 07.
Article
em En
| MEDLINE
| ID: mdl-26051004
ABSTRACT
Recently, several novel iridium complexes have been shown to catalyse group transfer reactions in a highly selective fashion. Rhodium complexes, and in particular dirhodium tetracarboxylate salts, have proven to be a remarkably useful class of catalysts for these reactions through several decades of development. Recent results suggest that iridium may offer opportunities to address challenges in this chemistry and provide complementary reactivity patterns. This tutorial review outlines the recent developments in Ir-catalyzed enantioselective group transfer chemistry with highlights on examples which display this unique reactivity.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Iminas
/
Irídio
/
Metano
Idioma:
En
Revista:
Chem Soc Rev
Ano de publicação:
2015
Tipo de documento:
Article
País de afiliação:
Estados Unidos