A Long-Lived Fe(III)-(Hydroperoxo) Intermediate in the Active H200C Variant of Homoprotocatechuate 2,3-Dioxygenase: Characterization by Mössbauer, Electron Paramagnetic Resonance, and Density Functional Theory Methods.

Meier, Katlyn K; Rogers, Melanie S; Kovaleva, Elena G; Mbughuni, Michael M; Bominaar, Emile L; Lipscomb, John D; Münck, Eckard

Meier, Katlyn K; Rogers, Melanie S; Kovaleva, Elena G; Mbughuni, Michael M; Bominaar, Emile L; Lipscomb, John D; Münck, Eckard.

Afiliação

Meier KK; Department of Chemistry, Carnegie Mellon University , Pittsburgh, Pennsylvania 15213, United States.
Rogers MS; Department of Biochemistry, Molecular Biology and Biophysics and Center for Metals in Biocatalysis, University of Minnesota , Minneapolis, Minnesota 55455, United States.
Kovaleva EG; Stanford Synchrotron Radiation Lightsource, 2575 Sand Hill Road, Menlo Park, California 94025, United States.
Mbughuni MM; Department of Biochemistry, Molecular Biology and Biophysics and Center for Metals in Biocatalysis, University of Minnesota , Minneapolis, Minnesota 55455, United States.
Bominaar EL; Department of Chemistry, Carnegie Mellon University , Pittsburgh, Pennsylvania 15213, United States.
Lipscomb JD; Department of Biochemistry, Molecular Biology and Biophysics and Center for Metals in Biocatalysis, University of Minnesota , Minneapolis, Minnesota 55455, United States.
Münck E; Department of Chemistry, Carnegie Mellon University , Pittsburgh, Pennsylvania 15213, United States.

Inorg Chem ; 54(21): 10269-80, 2015 Nov 02.

Article em En | MEDLINE | ID: mdl-26485328

Assuntos

Dioxigenases/química; Espectroscopia de Ressonância de Spin Eletrônica; Espectroscopia de Mossbauer

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Dioxigenases Tipo de estudo: Prognostic_studies Idioma: En Revista: Inorg Chem Ano de publicação: 2015 Tipo de documento: Article País de afiliação: Estados Unidos

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