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Visible-Light-Driven Photocatalytic Initiation of Radical Thiol-Ene Reactions Using Bismuth Oxide.
Fadeyi, Olugbeminiyi O; Mousseau, James J; Feng, Yiqing; Allais, Christophe; Nuhant, Philippe; Chen, Ming Z; Pierce, Betsy; Robinson, Ralph.
Afiliação
  • Fadeyi OO; Worldwide Medicinal Chemistry, Pfizer , 445 Eastern Point Road, Groton, Connecticut 06340, United States.
  • Mousseau JJ; Worldwide Medicinal Chemistry, Pfizer , 445 Eastern Point Road, Groton, Connecticut 06340, United States.
  • Feng Y; Worldwide Medicinal Chemistry, Pfizer , 445 Eastern Point Road, Groton, Connecticut 06340, United States.
  • Allais C; Worldwide Medicinal Chemistry, Pfizer , 445 Eastern Point Road, Groton, Connecticut 06340, United States.
  • Nuhant P; Worldwide Medicinal Chemistry, Pfizer , 445 Eastern Point Road, Groton, Connecticut 06340, United States.
  • Chen MZ; Worldwide Medicinal Chemistry, Pfizer , 445 Eastern Point Road, Groton, Connecticut 06340, United States.
  • Pierce B; Worldwide Medicinal Chemistry, Pfizer , 445 Eastern Point Road, Groton, Connecticut 06340, United States.
  • Robinson R; Worldwide Medicinal Chemistry, Pfizer , 445 Eastern Point Road, Groton, Connecticut 06340, United States.
Org Lett ; 17(23): 5756-9, 2015 Dec 04.
Article em En | MEDLINE | ID: mdl-26572219
ABSTRACT
A nontoxic and inexpensive photocatalytic initiation of anti-Markovnikov hydrothiolation of olefins using visible light is reported. This method is characterized by low catalyst loading, thereby enabling a mild and selective method for radical initiation in thiol-ene reactions between a wide scope of olefins and thiols.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2015 Tipo de documento: Article País de afiliação: Estados Unidos

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2015 Tipo de documento: Article País de afiliação: Estados Unidos