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Trigonal prismatic metal complexes: a not so rare coordination geometry?
Alcock, Leighton J; Cavigliasso, Germán; Willis, Anthony C; Stranger, Robert; Ralph, Stephen F.
Afiliação
  • Alcock LJ; School of Chemistry, University of Wollongong, Northfields Avenue, Wollongong 2522, Australia. sralph@uow.edu.au.
  • Cavigliasso G; Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory 0200, Australia.
  • Willis AC; Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory 0200, Australia.
  • Stranger R; Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory 0200, Australia.
  • Ralph SF; School of Chemistry, University of Wollongong, Northfields Avenue, Wollongong 2522, Australia. sralph@uow.edu.au.
Dalton Trans ; 45(22): 9036-40, 2016 May 31.
Article em En | MEDLINE | ID: mdl-27125359
The solid state structures of two metal complexes of a hexaamine macrobicyclic ligand, in which the metal ion has an exact trigonal prismatic geometry, have been determined. Theoretical calculations showed this is the most stable geometry for d(0), d(10) and high spin d(5) metal complexes of the ligand with M-N bond distances >∼2.35 Å.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2016 Tipo de documento: Article País de afiliação: Austrália
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2016 Tipo de documento: Article País de afiliação: Austrália