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Dihydrogen Splitting Using Dialkylsilylene-Based Frustrated Lewis Pairs.
Dong, Zhaowen; Li, Zhifang; Liu, Xupeng; Yan, Chenting; Wei, Ningka; Kira, Mitsuo; Müller, Thomas.
Afiliação
  • Dong Z; Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, No. 2318 Yuhangtang Rd. Hangzhou, 311121, Zhejiang, China.
  • Li Z; Institute of Chemistry, Carl von Ossietzky Universität Oldenburg, Carl-von-Ossietzky-Str. 9-11, 26129, Oldenburg, Germany.
  • Liu X; Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, No. 2318 Yuhangtang Rd. Hangzhou, 311121, Zhejiang, China.
  • Yan C; Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, No. 2318 Yuhangtang Rd. Hangzhou, 311121, Zhejiang, China.
  • Wei N; Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, No. 2318 Yuhangtang Rd. Hangzhou, 311121, Zhejiang, China.
  • Kira M; Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, No. 2318 Yuhangtang Rd. Hangzhou, 311121, Zhejiang, China.
  • Müller T; Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, No. 2318 Yuhangtang Rd. Hangzhou, 311121, Zhejiang, China.
Chem Asian J ; 12(11): 1204-1207, 2017 Jun 01.
Article em En | MEDLINE | ID: mdl-28195409
ABSTRACT
Isolable dialkylsilylene 5 reacts with dihydrogen in the presence of a small amount of a conventional Lewis acid (BPh3 , BEt3 ) or a base (PPh3 , PEt3 , NPh3 , NEt3 ) at low temperatures in a hydrocarbon solvent, giving the corresponding dihydrosilane 10 in high yields. Both 5/Lewis acid and Lewis base/5 pairs work as a frustrated Lewis pair (FLP) to split dihydrogen, being in accord with the amphoteric nature of silylene 5.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chem Asian J Ano de publicação: 2017 Tipo de documento: Article País de afiliação: China
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chem Asian J Ano de publicação: 2017 Tipo de documento: Article País de afiliação: China