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Chemical Vapor Deposition Synthesis and Terahertz Photoconductivity of Low-Band-Gap N = 9 Armchair Graphene Nanoribbons.
Chen, Zongping; Wang, Hai I; Teyssandier, Joan; Mali, Kunal S; Dumslaff, Tim; Ivanov, Ivan; Zhang, Wen; Ruffieux, Pascal; Fasel, Roman; Räder, Hans Joachim; Turchinovich, Dmitry; De Feyter, Steven; Feng, Xinliang; Kläui, Mathias; Narita, Akimitsu; Bonn, Mischa; Müllen, Klaus.
Afiliação
  • Chen Z; Max Planck Institute for Polymer Research , Ackermannweg 10, D-55128 Mainz, Germany.
  • Wang HI; Institute of Physics, Johannes Gutenberg-University Mainz , Staudingerweg 7, 55128 Mainz, Germany.
  • Teyssandier J; Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven , Celestijnenlaan 200 F, B-3001 Leuven, Belgium.
  • Mali KS; Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven , Celestijnenlaan 200 F, B-3001 Leuven, Belgium.
  • Dumslaff T; Max Planck Institute for Polymer Research , Ackermannweg 10, D-55128 Mainz, Germany.
  • Ivanov I; Max Planck Institute for Polymer Research , Ackermannweg 10, D-55128 Mainz, Germany.
  • Zhang W; Max Planck Institute for Polymer Research , Ackermannweg 10, D-55128 Mainz, Germany.
  • Ruffieux P; Empa, Swiss Federal Laboratories for Materials Science and Technology , nanotech@surfaces Laboratory, 8600 Dübendorf, Switzerland.
  • Fasel R; Empa, Swiss Federal Laboratories for Materials Science and Technology , nanotech@surfaces Laboratory, 8600 Dübendorf, Switzerland.
  • Räder HJ; Department of Chemistry and Biochemistry, University of Bern , 3012 Bern, Switzerland.
  • Turchinovich D; Max Planck Institute for Polymer Research , Ackermannweg 10, D-55128 Mainz, Germany.
  • De Feyter S; Max Planck Institute for Polymer Research , Ackermannweg 10, D-55128 Mainz, Germany.
  • Feng X; Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven , Celestijnenlaan 200 F, B-3001 Leuven, Belgium.
  • Kläui M; Center for Advancing Electronics Dresden and Department of Chemistry and Food Chemistry, Technische Universität Dresden , Mommsenstrasse 4, D-01062 Dresden, Germany.
  • Narita A; Institute of Physics, Johannes Gutenberg-University Mainz , Staudingerweg 7, 55128 Mainz, Germany.
  • Bonn M; Max Planck Institute for Polymer Research , Ackermannweg 10, D-55128 Mainz, Germany.
  • Müllen K; Max Planck Institute for Polymer Research , Ackermannweg 10, D-55128 Mainz, Germany.
J Am Chem Soc ; 139(10): 3635-3638, 2017 03 15.
Article em En | MEDLINE | ID: mdl-28248492
ABSTRACT
Recent advances in bottom-up synthesis of atomically defined graphene nanoribbons (GNRs) with various microstructures and properties have demonstrated their promise in electronic and optoelectronic devices. Here we synthesized N = 9 armchair graphene nanoribbons (9-AGNRs) with a low optical band gap of ∼1.0 eV and extended absorption into the infrared range by an efficient chemical vapor deposition process. Time-resolved terahertz spectroscopy was employed to characterize the photoconductivity in 9-AGNRs and revealed their high intrinsic charge-carrier mobility of approximately 350 cm2·V-1·s-1.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Alemanha

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Alemanha