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Synthesis and Dual-Emission Feature of Salen-Al/Triarylborane Dyads.
Kwak, Sang Woo; Choi, Byung Hoon; Lee, Ji Hye; Hwang, Hyonseok; Lee, Junseong; Kwon, Hyoshik; Chung, Yongseog; Lee, Kang Mun; Park, Myung Hwan.
Afiliação
  • Choi BH; Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University , Chuncheon, Gangwon 24341, Republic of Korea.
  • Lee JH; Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University , Chuncheon, Gangwon 24341, Republic of Korea.
  • Hwang H; Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University , Chuncheon, Gangwon 24341, Republic of Korea.
  • Lee J; Department of Chemistry, Chonnam National University , Gwangju 61186, Republic of Korea.
  • Lee KM; Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University , Chuncheon, Gangwon 24341, Republic of Korea.
Inorg Chem ; 56(11): 6039-6043, 2017 Jun 05.
Article em En | MEDLINE | ID: mdl-28537404
ABSTRACT
Novel salen-Al/triarylborane dyad complexes were prepared and characterized with their corresponding mononuclear compounds. The UV-vis and photoluminescence experiments for dyads exhibited photoinduced energy transfer from borane to the salen-Al moiety in an intramolecular manner. Theoretical calculation and fluoride titration results further supported these intramolecular energy-transfer features.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2017 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2017 Tipo de documento: Article