Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex.
J Am Chem Soc
; 139(41): 14372-14375, 2017 10 18.
Article
em En
| MEDLINE
| ID: mdl-28960973
ABSTRACT
A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]- (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+â¢)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+â¢). 2 is a competent oxidant in C-H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1.
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Base de dados:
MEDLINE
Assunto principal:
Elétrons
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Ferro
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2017
Tipo de documento:
Article