Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged MII (M = Mn, Ni) coordination polymers.
Dalton Trans
; 47(3): 845-851, 2018 Jan 15.
Article
em En
| MEDLINE
| ID: mdl-29250623
ABSTRACT
MII (M = Mn, Ni) coordination frameworks, singly linked by end-on azide ligands, were prepared by employing the long, flexible spacer ligand, p-XBP4. These two-dimensional layer structures underwent reversible crystal-to-amorphous phase transformations during the hydration-dehydration process. Moreover, the magnetic nature changes from antiferromagnetic to ferromagnetic coupling when moving from Mn to Ni.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2018
Tipo de documento:
Article