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Synthesis of Acyl Azides from 1,3-Diketones via Oxidative Cleavage of Two C-C Bonds.
Yu, Tian-Yang; Zheng, Zhao-Jing; Dang, Tong-Tong; Zhang, Fang-Xia; Wei, Hao.
Afiliação
  • Yu TY; Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of the Ministry of Education, College of Chemistry and Materials Science , Northwest University , Xi'an 710127 , P.R. China.
  • Zheng ZJ; State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering , Lanzhou University , Lanzhou 730000 , P.R. China.
  • Dang TT; Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of the Ministry of Education, College of Chemistry and Materials Science , Northwest University , Xi'an 710127 , P.R. China.
  • Zhang FX; Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of the Ministry of Education, College of Chemistry and Materials Science , Northwest University , Xi'an 710127 , P.R. China.
  • Wei H; Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of the Ministry of Education, College of Chemistry and Materials Science , Northwest University , Xi'an 710127 , P.R. China.
J Org Chem ; 83(17): 10589-10594, 2018 Sep 07.
Article em En | MEDLINE | ID: mdl-30080043
A metal-free PhI(OAc)2-mediated method for the synthesis of acyl azides through oxidative cleavage of 1,3-diketones is described. This method is shown to have a broad substrate scope, providing a useful tool for multiproduct synthesis in a single procedure. A possible reaction pathway is proposed based on mechanistic studies.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2018 Tipo de documento: Article